Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)

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dc.contributor.author Matesanz, Ana I.
dc.contributor.author Pastor, César J.
dc.contributor.author Souza, Pilar
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2015-04-17T07:50:23Z
dc.date.available 2015-04-17T07:50:23Z
dc.date.issued 2007-01-01
dc.identifier.citation Inorganic Chemistry Communications 10.1 (2007): 97-100 es_ES
dc.identifier.issn 1387-7003 (print) es_ES
dc.identifier.uri http://hdl.handle.net/10486/665174
dc.description NOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Inorganic Chemistry Communications 10.1 (2007): 97-100 DOI http://dx.doi.org/10.1016/j.inoche.2006.09.016 es_ES
dc.description.abstract A novel tetranuclear [Pd4(μ2-η2-S2)(H2L1)2] complex, where H2L1 is the anion of 3,5-diacetyl-1,2,4-triazole bis(4-ethylthiosemicarbazone), was synthesized and structurally characterized by single crystal X-ray diffraction. The molecular structure shows an unexpected μ2-η2-S2 bridge, which is shared by all the four palladium atoms. Each trideprotonate 3,5-diacetyl-1,2,4-triazole bis(4-ethylthiosemicarbazone) ligand acts as a hexadentate in a symmetrical manner bridging two metal ions through the two adjacent nitrogen atoms of the central triazole ring. The molecular packing is characterized by hydrogen bond interactions to form a 3D supramolecular architecture with channels running down the c* axis in which the lattice water molecules are encapsulated es_ES
dc.description.sponsorship We are grateful to Ministerio de Sanidad y Consumo, Instituto de Salud Carlos III (PI040354) and Comunidad Autónoma de Madrid (GR/SAL/0180/2004) of Spain for financial support es_ES
dc.format.extent 4 pag. es_ES
dc.format.mimetype application/pdf es_ES
dc.language.iso eng es_ES
dc.publisher Elsevier B.V. es_ES
dc.relation.ispartof Inorganic Chemistry Communications es_ES
dc.rights © 2010 Elsevier B.V. All rights reserved es_ES
dc.subject.other 1,2,4-triazole es_ES
dc.subject.other Bis(thiosemicarbazone) es_ES
dc.subject.other Crystal structure es_ES
dc.subject.other Disulphide-bridged es_ES
dc.subject.other Tetranuclear palladium(II) complexes es_ES
dc.subject.other Water molecules encapsulated es_ES
dc.title Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone) es_ES
dc.type article es_ES
dc.subject.eciencia Química es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.inoche.2006.09.016 es_ES
dc.identifier.doi 10.1016/j.inoche.2006.09.016 es_ES
dc.identifier.publicationfirstpage 97 es_ES
dc.identifier.publicationissue 1 es_ES
dc.identifier.publicationlastpage 100 es_ES
dc.identifier.publicationvolume 10 es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion es_ES
dc.rights.cc Reconocimiento – NoComercial – SinObraDerivada es_ES
dc.rights.accessRights openAccess es_ES


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