Unprecedented Pt(II) complex of an asymmetric 2,6-diacetylpyridine bis(4N-substituted thiosemicarbazone) ligand

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dc.contributor.author Matesanz, Ana I.
dc.contributor.author Souza, Pilar
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2015-04-17T07:51:14Z
dc.date.available 2015-04-17T07:51:14Z
dc.date.issued 2013-01-01
dc.identifier.citation Inorganic Chemistry Communications 27 (2013): 5-8 en_US
dc.identifier.issn 1387-7003 (print) es_ES
dc.identifier.uri http://hdl.handle.net/10486/665175
dc.description NOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Inorganic Chemistry Communications 27 (2013): 5-8 DOI http://dx.doi.org/10.1016/j.inoche.2012.10.022 en_US
dc.description.abstract Reaction of 2,6-diacetylpyridine bis(4N-o- tolylthiosemicarbazone), H2L1, with K2PtCl 4 and further recrystallization in DMSO/MeOH of the [PtL1] complex obtained, led to the isolation of the novel platinum complex, [PtL 2], which was structurally characterized by single crystal X-ray diffraction. The molecular structure shows that the ligand has undergone an unexpected chemical transformation viz. reduction of one of the terminal phenyl rings into cyclohexyl. The resulted asymmetrical ligand acts a dianionic tetradentate donor, coordinating to the platinum (II) center in a square planar geometry through the Npyridinic atom and the Niminic and the S atoms from one thiosemicarbazone arm, the fourth coordination position is occupied by the Nhydrazinic atom of the other arm en_US
dc.description.sponsorship We are grateful to Ministerio de Economía y Competitividad. Instituto de Salud Carlos III of Spain (PI080525 and PI1100659) for financial support en_US
dc.format.extent 4 pag. en_US
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher Elsevier B.V. en_US
dc.relation.ispartof Inorganic Chemistry Communications en_US
dc.rights © 2012 Elsevier B.V. All rights reserved en_US
dc.subject.other 2,6-diacetylpyridine en_US
dc.subject.other Asymmetric N3S coordination en_US
dc.subject.other Bis(thiosemicarbazone) en_US
dc.subject.other Platinum(II) complexes en_US
dc.subject.other Thiol function en_US
dc.subject.other X-ray diffraction en_US
dc.title Unprecedented Pt(II) complex of an asymmetric 2,6-diacetylpyridine bis(4N-substituted thiosemicarbazone) ligand en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.inoche.2012.10.022 es_ES
dc.identifier.doi 10.1016/j.inoche.2012.10.022 es_ES
dc.identifier.publicationfirstpage 5 es_ES
dc.identifier.publicationlastpage 8 es_ES
dc.identifier.publicationvolume 27 es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.cc Reconocimiento – NoComercial – SinObraDerivada es_ES
dc.rights.accessRights openAccess en

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