Synthesis and complementary self-association of novel lipophilic π-conjugated nucleoside oligomers
Entity
UAM. Departamento de Química OrgánicaPublisher
Royal Society of ChemistryDate
2015-04-21Citation
10.1039/c5ob00098j
Organic and Biomolecular Chemistry 13.15 (2015): 4506-4513
ISSN
1477-0520 (print); 1477-0539 (on line)DOI
10.1039/c5ob00098jFunded by
Funding from the European Research Council (ERC-StG 279548) and MINECO (CTQ2011-23659) is gratefully acknowledgedProject
info:eu-repo/grantAgreement/EC/FP7/279548Editor's Version
http://dx.doi.org/10.1039/c5ob00098jSubjects
QuímicaNote
The following article appeared in Organic and Biomolecular Chemistry 13.15 (2015): 4506-4513 and may be found at http://dx.doi.org/10.1039/c5ob00098j, reproduced by permission of The Royal Society of ChemistryRights
© 2015 The Royal Society of ChemistryAbstract
A series of lipophilic nucleosides comprising natural and non-natural bases that are π-conjugated to a short oligophenylene-ethynylene fragment has been synthesized. These bases comprise guanosine, isoguanosine, and 2-aminoadenosine as purine heterocycles, and cytidine, isocytosine and uridine as complementary pyrimidine bases. The hydrogen-bonding dimerization and association processes between complementary bases were also studied by 1H NMR and absorption spectroscopy in order to obtain the relevant association constants
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Google Scholar:Camacho García, J.
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López-Pérez, Ana M.
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González Rodríguez, David
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