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Determination of energy-transfer distributions in ionizing ion-molecule collisions

dc.contributor.authorMaclot, S.
dc.contributor.authorDelaunay, R.
dc.contributor.authorPiekarski, Dariusz Grzegorz
dc.contributor.authorDomaracka, A.
dc.contributor.authorHuber, B. A.
dc.contributor.authorAdoui, L.
dc.contributor.authorMartín García, Fernando 
dc.contributor.authorAlcamí Pertejo, Manuel 
dc.contributor.authorAvaldi, L.
dc.contributor.authorBolognesi, P.
dc.contributor.authorDíaz-Tendero Victoria, Sergio 
dc.contributor.authorRousseau, P.
dc.contributor.otherUAM. Departamento de Químicaes_ES
dc.date.accessioned2017-10-20T16:05:52Z
dc.date.available2017-10-20T16:05:52Z
dc.date.issued2016-08-08
dc.identifier.citationPhysical Review Letters 117.7 (2016): 073201en_US
dc.identifier.issn0031-9007 (print)es_ES
dc.identifier.issn1079-7114 (online)es_ES
dc.identifier.urihttp://hdl.handle.net/10486/679913
dc.description.abstractThe ionization and fragmentation of the nucleoside thymidine in the gas phase has been investigated by combining ion collision with state-selected photoionization experiments and quantum chemistry calculations. The comparison between the mass spectra measured in both types of experiments allows us to accurately determine the distribution of the energy deposited in the ionized molecule as a result of the collision. The relation of two experimental techniques and theory shows a strong correlation between the excited states of the ionized molecule with the computed dissociation pathways, as well as with charge localization or delocalizationen_US
dc.description.sponsorshipWe thank F. Noury, S. Guillous, R. Richter, M. Coreno, and K. Prince for support as well as L. J. Avaldi for advice in the statistical analysis of the data. We acknowledge the allocation of computer time at the Centro de Computación Científica at the Universidad Autónoma de Madrid (CCCUAM). This work was partially supported by the projects FIS2013-42002-R and CTQ2013-43698-P (MINECO), NANOFRONTMAG (CAM), PHC Galilée 28137PE, and an Advanced Grant of the European Research Council XCHEM No. 290853. Research was conducted in the framework of the International Associated Laboratory (LIA) “Fragmentation dynamics of complex molecular systems—DYNAMO” and in the COST actions XLIC (CM1204) and Nano-IBCT (MP1002). D. G. P. acknowledges the FPI grant of the Universidad Autónoma de Madrid. S. D.-T. gratefully acknowledges the “Ramón y Cajal” program of the Spanish Ministerio de Educación y Cienciaen_US
dc.format.extent6 pág.es_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherAmerican Physical Societyen_US
dc.relation.ispartofPhysical Review Lettersen_US
dc.rights© 2016 American Physical Societyen_US
dc.subject.otherCharge localizationen_US
dc.subject.otherDelocalizationsen_US
dc.subject.otherDissociation pathwaysen_US
dc.subject.otherExperimental techniquesen_US
dc.titleDetermination of energy-transfer distributions in ionizing ion-molecule collisionsen_US
dc.typearticleen
dc.subject.ecienciaQuímicaes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1103/PhysRevLett.117.073201es_ES
dc.identifier.doi10.1103/PhysRevLett.117.073201es_ES
dc.identifier.publicationfirstpage1es_ES
dc.identifier.publicationissue7es_ES
dc.identifier.publicationlastpage6es_ES
dc.identifier.publicationvolume117es_ES
dc.relation.projectIDGobierno de España. FIS2013-42002-Res_ES
dc.relation.projectIDGobierno de España. CTQ2013-43698-Pes_ES
dc.relation.projectIDComunidad de Madrid. S2013/MIT-2850/NANOFRONTMAG-CMes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/290853es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/321971es_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.rights.accessRightsopenAccessen
dc.authorUAMAlcami Pertejo, Manuel (259527)
dc.authorUAMDíaz-Tendero Victoria, Sergio (262857)
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMCentro de Investigación en Física de la Materia Condensada (IFIMAC)


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