dc.contributor.author | Galego, Javier | |
dc.contributor.author | García Vidal, Fco. José | |
dc.contributor.author | Feist, Johannes | |
dc.contributor.other | UAM. Departamento de Física Teórica de la Materia Condensada | es_ES |
dc.contributor.other | UAM. Centro de Investigación en Fisica de la Materia Condensada (IFIMAC) | es_ES |
dc.date.accessioned | 2018-11-28T12:09:01Z | |
dc.date.available | 2018-11-28T12:09:01Z | |
dc.date.issued | 2017-09-27 | |
dc.identifier.citation | Physical Review Letters 119.13 (2017): 136001 | en_US |
dc.identifier.issn | 0031-9007 (print) | es_ES |
dc.identifier.issn | 1079-7114 (online) | es_ES |
dc.identifier.uri | http://hdl.handle.net/10486/685763 | |
dc.description.abstract | The second law of photochemistry states that, in most cases, no more than one molecule is activated for an excited-state reaction for each photon absorbed by a collection of molecules. In this Letter, we demonstrate that it is possible to trigger a many-molecule reaction using only one photon by strongly coupling the molecular ensemble to a confined light mode. The collective nature of the resulting hybrid states of the system (the so-called polaritons) leads to the formation of a polaritonic "supermolecule" involving the degrees of freedom of all molecules, opening a reaction path on which all involved molecules undergo a chemical transformation. We theoretically investigate the system conditions for this effect to take place and be enhanced. | en_US |
dc.description.sponsorship | This work has been funded by the European Research Council
under Grants No. ERC-2011-AdG-290981 and No. ERC-
2016-STG-714870, by the European Union Seventh
Framework Programme under Grant No. FP7-PEOPLE-
2013-CIG-618229, and the Spanish MINECO under
Contract No. MAT2014-53432-C5-5-R and the “María
de Maeztu” program for Units of Excellence in R&D
(MDM-2014-0377). | en_US |
dc.format.extent | 6 pag. | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | American Physical Society | en_US |
dc.relation.ispartof | Physical Review Letters | en_US |
dc.rights | © 2017 American Physical Society | en_US |
dc.subject.other | Molecules | en_US |
dc.subject.other | Photon | en_US |
dc.subject.other | Chemical transformation | en_US |
dc.subject.other | Supermolecule | en_US |
dc.title | Many-molecule reaction triggered by a single photon in polaritonic chemistry | en_US |
dc.type | article | en |
dc.subject.eciencia | Física | es_ES |
dc.relation.publisherversion | https://doi.org/10.1103/PhysRevLett.119.136001 | es_ES |
dc.identifier.doi | 10.1103/PhysRevLett.119.136001 | es_ES |
dc.identifier.publicationfirstpage | 136001-1 | es_ES |
dc.identifier.publicationissue | 13 | es_ES |
dc.identifier.publicationlastpage | 136001-6 | es_ES |
dc.identifier.publicationvolume | Physical Review Letters | en_US |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/290881 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/714870 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/630996 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/618229 | es_ES |
dc.relation.projectID | Gobierno de España. MAT2014-53432-C5-5-R | es_ES |
dc.relation.projectID | Gobierno de España. FIS2015-64951-R | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.rights.accessRights | openAccess | es_ES |
dc.authorUAM | Feist, Johannes Maximilian (264839) | |
dc.facultadUAM | Facultad de Ciencias | |
dc.institutoUAM | Centro de Investigación en Física de la Materia Condensada (IFIMAC) | |