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dc.contributor.authorGalego, Javier
dc.contributor.authorGarcía Vidal, Fco. José 
dc.contributor.authorFeist, Johannes
dc.contributor.otherUAM. Departamento de Física Teórica de la Materia Condensadaes_ES
dc.contributor.otherUAM. Centro de Investigación en Fisica de la Materia Condensada (IFIMAC)es_ES
dc.date.accessioned2018-11-28T12:09:01Z
dc.date.available2018-11-28T12:09:01Z
dc.date.issued2017-09-27
dc.identifier.citationPhysical Review Letters 119.13 (2017): 136001en_US
dc.identifier.issn0031-9007 (print)es_ES
dc.identifier.issn1079-7114 (online)es_ES
dc.identifier.urihttp://hdl.handle.net/10486/685763
dc.description.abstractThe second law of photochemistry states that, in most cases, no more than one molecule is activated for an excited-state reaction for each photon absorbed by a collection of molecules. In this Letter, we demonstrate that it is possible to trigger a many-molecule reaction using only one photon by strongly coupling the molecular ensemble to a confined light mode. The collective nature of the resulting hybrid states of the system (the so-called polaritons) leads to the formation of a polaritonic "supermolecule" involving the degrees of freedom of all molecules, opening a reaction path on which all involved molecules undergo a chemical transformation. We theoretically investigate the system conditions for this effect to take place and be enhanced.en_US
dc.description.sponsorshipThis work has been funded by the European Research Council under Grants No. ERC-2011-AdG-290981 and No. ERC- 2016-STG-714870, by the European Union Seventh Framework Programme under Grant No. FP7-PEOPLE- 2013-CIG-618229, and the Spanish MINECO under Contract No. MAT2014-53432-C5-5-R and the “María de Maeztu” program for Units of Excellence in R&D (MDM-2014-0377).en_US
dc.format.extent6 pag.es_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherAmerican Physical Societyen_US
dc.relation.ispartofPhysical Review Lettersen_US
dc.rights© 2017 American Physical Societyen_US
dc.subject.otherMoleculesen_US
dc.subject.otherPhotonen_US
dc.subject.otherChemical transformationen_US
dc.subject.otherSupermoleculeen_US
dc.titleMany-molecule reaction triggered by a single photon in polaritonic chemistryen_US
dc.typearticleen
dc.subject.ecienciaFísicaes_ES
dc.relation.publisherversionhttps://doi.org/10.1103/PhysRevLett.119.136001es_ES
dc.identifier.doi10.1103/PhysRevLett.119.136001es_ES
dc.identifier.publicationfirstpage136001-1es_ES
dc.identifier.publicationissue13es_ES
dc.identifier.publicationlastpage136001-6es_ES
dc.identifier.publicationvolumePhysical Review Lettersen_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/290881es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/714870es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/630996es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/618229es_ES
dc.relation.projectIDGobierno de España. MAT2014-53432-C5-5-Res_ES
dc.relation.projectIDGobierno de España. FIS2015-64951-Res_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.rights.accessRightsopenAccesses_ES
dc.authorUAMFeist, Johannes Maximilian (264839)
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMCentro de Investigación en Física de la Materia Condensada (IFIMAC)


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