Novel Oxidative Ugi Reaction for the Synthesis of Highly Active, Visible-Light, Imide-Acridinium Organophotocatalysts
Entity
UAM. Departamento de Química OrgánicaPublisher
Wiley-VCH VerlagDate
2018-06-08Citation
10.1002/chem.201802830
Chemistry - A European Journal 24.48 (2018): 12509-12514
ISSN
0947-6539DOI
10.1002/chem.201802830Funded by
The Boehringer Ingelheim Stiftung (Exploration Grant), the Deutsche Forschungsgemeinschaft (DFG), the COST Action “C− H activation in organic Synthesis (CHAOS)” (CA15106) and Spanish Government (CTQ2015-64561-R) are gratefully acknowledged for generous supportProject
Gobierno de España. CTQ2015-64561-REditor's Version
https://doi.org/10.1002/chem.201802830Subjects
C−H functionalization; Photocatalysis; Acridinium salts; Oxidation; Multicomponent reactions; QuímicaNote
This is the peer reviewed version of the following article: Gini, Andrea, et al. "Novel Oxidative Ugi Reaction for the Synthesis of Highly Active, Visible‐Light, Imide‐Acridinium Organophotocatalysts." Chemistry–A European Journal 24.48 (2018): 12509-12514, which has been published in final form at https://doi.org/10.1002/chem.201802830. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived VersionsRights
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimAbstract
A newly designed class of acridinium-based organophotocatalysts bearing an imide group at the C9-position is presented. To achieve these unprecedented structures, a synthetic strategy based on a novel straightforward oxidative Ugi-type reaction at the benzylic position of C9-unsubstituted acridanes was developed. The introduction of the imide-unit affords a notable photocatalytic activity enhancement, allowing efficient transformations in different oxidative and reductive visible-light catalytic reactions
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Google Scholar:Gini, Andrea
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Uygur, Mustafa
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Rigotti, Thomas
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Alemán Lara, José Julián
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García Mancheño, Olga
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