UAM_Biblioteca

View Item 

Show simple item record

Asymmetric synthesis of Rauhut-Currier-type esters via Mukaiyama-Michael reaction to acylphosphonates under bifunctional catalysis

dc.contributor.authorLaina-Martín, Víctor
dc.contributor.authorDel Río-Rodríguez, Roberto
dc.contributor.authorDíaz-Tendero Victoria, Sergio 
dc.contributor.authorFernández-Salas, Jose A.
dc.contributor.authorAlemán Lara, José Julián 
dc.contributor.otherUAM. Departamento de Químicaes_ES
dc.contributor.otherUAM. Departamento de Química Orgánicaes_ES
dc.date.accessioned2019-04-08T09:01:11Z
dc.date.available2019-04-08T09:01:11Z
dc.date.issued2018-10-23
dc.identifier.citationChemical Communications 54.99 (2018): 13941-13944en_US
dc.identifier.issn1359-7345 (print)en_US
dc.identifier.issn1364-548X (online)en_US
dc.identifier.urihttp://hdl.handle.net/10486/687223
dc.description.abstractA highly enantioselective organocatalytic Mukaiyama-Michael reaction of silyloxy dienes and α,β-unsaturated acyl phosphonates under bifunctional organocatalysis is presented. The new reactivity triggered by the catalyst conducted to Rauhut-Currier type esters, via a formal conjugate addition to α,β-unsaturated esters. This protocol proceeds under mild conditions with complete regioselectivity and excellent enantiocontrolen_US
dc.description.sponsorshipWe are grateful to the Spanish Government (CTQ2015-64561-R and CTQ2016-76061-P) and the European Research Council (ERCCG-UNBICAT, contract number: 647550). J. A. F.-S. and V. L.-M. thank the Spanish Government for a Juan de la Cierva Contract and the Universidad Auto´noma de Madrid for a predoctoral fellowship (FPI-UAM), respectively. Financial support from the Spanish Ministry of Economy and Competitiveness, through the ‘‘Maria de Maeztu’’ Program of Excellence in R&D (MDM-2014-0377), is also acknowledged. We acknowledge the generous allocation of computing time at the CCC (UAM)en_US
dc.format.extent5 pag.en_US
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofChemical Communicationsen_US
dc.rights© 2018 The Royal Society of Chemistryen_US
dc.subject.otherAsymmetric synthesisen_US
dc.subject.otherCatalysisen_US
dc.subject.otherChemical structureen_US
dc.subject.otherChemical parametersen_US
dc.subject.otherChromatographyen_US
dc.subject.otherEnantioselectivityen_US
dc.subject.otherRegioselectivityen_US
dc.subject.otherMukaiyama Michael reactionen_US
dc.titleAsymmetric synthesis of Rauhut-Currier-type esters via Mukaiyama-Michael reaction to acylphosphonates under bifunctional catalysisen_US
dc.typearticleen
dc.subject.ecienciaQuímicaes_ES
dc.relation.publisherversionhttps://doi.org/10.1039/c8cc07561aes_ES
dc.identifier.doi10.1039/c8cc07561aes_ES
dc.identifier.publicationfirstpage13941es_ES
dc.identifier.publicationissue99es_ES
dc.identifier.publicationlastpage13944es_ES
dc.identifier.publicationvolume54es_ES
dc.relation.projectIDGobierno de España. CTQ2015-64561-Res_ES
dc.relation.projectIDGobierno de España. CTQ2016-76061-Pes_ES
dc.relation.projectIDGobierno de España. MDM-2014-0377es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/647550/EU//UNBICATen_US
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.rights.ccReconocimiento – NoComerciales_ES
dc.rights.accessRightsopenAccessen
dc.authorUAMDíaz-Tendero Victoria, Sergio (262857)
dc.authorUAMLaina Martín, Víctor (278891)
dc.authorUAMAleman Lara, José Julián (262855)es_ES
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMCentro de Investigación en Física de la Materia Condensada (IFIMAC)
dc.institutoUAMInstituto de Investigación Avanzada en Ciencias Químicas (IAdChem)


Files in this item

Thumbnail
Name:
asymmetric_laina_chc_2018.pdf
Size:
3.071Mb
Format:
PDF

This item appears in the following Collection(s)

Show simple item record