CWPO of bisphenol A with iron catalysts supported on microporous carbons from grape seeds activation

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dc.contributor.author Mena, Ismael F.
dc.contributor.author Diaz, Elena
dc.contributor.author Rodriguez, Juan J.
dc.contributor.author Mohedano, Angel F.
dc.contributor.other UAM. Departamento de Ingeniería Química es_ES
dc.contributor.other UAM. Departamento de Química Física Aplicada es_ES
dc.date.accessioned 2019-05-29T11:03:47Z
dc.date.available 2019-05-29T11:03:47Z
dc.date.issued 2017-06-15
dc.identifier.citation Chemical Engineering Journal 318 (2017): 153-160 en_US
dc.identifier.issn 1873-3212 (online) en_US
dc.identifier.issn 1385-8947 (print) en_US
dc.identifier.uri http://hdl.handle.net/10486/687642
dc.description This accepted manuscript is available under a CC BY-NC-ND licence after the 24 months embargo period en_US
dc.description.abstract The catalytic wet peroxide oxidation (CWPO) of bisphenol A (BPA) with Fe catalysts supported on activated carbon from grape seeds (GS) has been studied. The GS were pyrolized (N2, 600 °C, 2 h) and subjected to activation upon partial gasification with air (400 °C, 2 h). Oxidized samples of the char and activated carbon were also obtained upon treatment with HNO3. The Fe catalysts were prepared by incipient wetness impregnation with ferric nitrate solution. They showed narrow microporosity, with surface area values ≈350–500 m2 g−1 and total iron contents between 2.8 and 4.2% wt. The CWPO experiments were carried out at 50–80 °C. The best catalyst allowed complete conversion of BPA (100 mg L−1) and a 60% TOC reduction in 3 h reaction time at 80 °C and the theoretical stoichiometric amount of H2O2 (530 mg L−1). The ecotoxicity of the effluent was negligible and the biodegradability was highly improved. In a long-term experiment (100 h), the catalyst suffered a loss of activity upon the early stages on stream (≈15 h), where about 20% of Fe was lost, followed by a highly stable behavior for the rest of the experiment en_US
dc.description.sponsorship The authors wish to thank the Spanish MINECO and Comunidad de Madrid for the financial support through the projects CTM2013-43803-P and S2013/MAE-2716, respectively. I. F. Mena wishes to thank the MINECO and the ESF for a research grant en_US
dc.format.extent 28 pag. en_US
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher Elsevier en_US
dc.relation.ispartof Chemical Engineering Journal en_US
dc.rights © 2016 Elsevier B.V. All rights reserved en_US
dc.subject.other Biochar en_US
dc.subject.other Bisphenol A en_US
dc.subject.other Fe catalysts en_US
dc.subject.other Grape seeds en_US
dc.subject.other Heterogeneous Fenton en_US
dc.subject.other Stability en_US
dc.title CWPO of bisphenol A with iron catalysts supported on microporous carbons from grape seeds activation en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.date.embargoend 2019-06-15
dc.relation.publisherversion https://doi.org/10.1016/j.cej.2016.06.029 es_ES
dc.identifier.doi 10.1016/j.cej.2016.06.029 es_ES
dc.identifier.publicationfirstpage 153 es_ES
dc.identifier.publicationlastpage 160 es_ES
dc.identifier.publicationvolume 318 es_ES
dc.relation.projectID Gobierno de España. CTM2013-43803-P es_ES
dc.relation.projectID Comunidad de Madrid. S2013/MAE-2716/REMTAVARES es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.cc Reconocimiento – NoComercial – SinObraDerivada es_ES
dc.rights.accessRights openAccess en


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