Reversible transformation between Cu(i)-thiophenolate coordination polymers displaying luminescence and electrical properties
Entity
UAM. Departamento de Química InorgánicaPublisher
Royal Society of ChemistryDate
2019-05-28Citation
10.1039/C9CE00313D
CrystEngComm 21.20 (2019): 3232-3239
ISSN
1466-8033DOI
10.1039/C9CE00313DFunded by
This work was supported in part by MICINN (grant MAT2016-77608-C3-1-P)Project
Gobierno de España. MAT2016-77608-C3-1-PEditor's Version
https://doi.org/10.1039/C9CE00313DSubjects
Copper compounds; Coordination reactions; Luminescence; Polymers; QuímicaRights
© The Royal Society of Chemistry 2019Abstract
A one-dimensional [Cu6I3(TP)3(MeCN)2]n (1) coordination polymer (CP) has been prepared by the direct reaction between CuI and a thiophenol (TP) ligand. The reversible conversion reaction between 1 and the homoleptic 1D-CP [Cu(TP)]n (2) is observed in acetonitrile upon controlling the CuI ratio. Interestingly, CPs 1 and 2 are multifunctional materials showing both luminescence and electrical properties. Photoluminescence measurements reveal that 1 and 2 are emissive in the blue and the red regions, respectively. Additionally, both materials show electrical conductivity at room temperature (1.2 × 10-8 for 1 and 3.7 × 10-4 S cm-1 for 2) indicating a semiconductor behaviour. DFT calculations have been used to rationalise these observations
Files in this item
Size
1.080Mb
Format
PDF
Description
Electronic Supplementary Material
Google Scholar:Troyano, Javier
-
Castillo, Óscar
-
Amo Ochoa, María Pilar
-
Martínez, J. Ignacio
-
Zamora Abanades, Félix Juan
-
Delgado Gil, Salomé
This item appears in the following Collection(s)
Related items
Showing items related by title, author, creator and subject.