Fast and efficient direct formation of size-controlled nanostructures of coordination polymers based on copper(i)-iodine bearing functional pyridine terminal ligands
Entity
UAM. Departamento de Química InorgánicaPublisher
Royal Society of ChemistryDate
2018-04-28Citation
10.1039/C8DT00083B
Dalton Transactions 47.16 (2018): 5607-5613
ISSN
1477-9226DOI
10.1039/C8DT00083BFunded by
We are grateful for financial support from the Spanish Ministerio de Economía y Competitividad (MAT2013-46502-C2-2P, MAT2016-75883-C2-2-P, BES-2015-071534) and also to the scientific computing center (CCC) of the Autónoma University of Madrid for their timeProject
Gobierno de España. MAT2016-75883-C2-2-P; Gobierno de España. BES-2015-071534; Gobierno de España. MAT2013-46502-C2-2-PEditor's Version
https://doi.org/10.1039/C8DT00083BSubjects
Copper compounds; Polymers; Nanostructures; Ligands; Iodine; QuímicaRights
© 2018 The Royal Society of ChemistryAbstract
We report on the direct formation of 1D nanostructures of two coordination polymers based on copper(i)-iodine double chains decorated with ethyl isonicotinate or 2-amino-5-nitropyridine as terminal ligands. The use of different reaction conditions, e.g. energy of the formation process, solvents, and/or concentration of reactants, has allowed the control of the size of the fibres and ribbons directly formed in this process going from micron- to submicron- up to nano-size. We show experiments that direct the formation of materials kinetically versus thermodynamically controlled, adjusting simple experimental parameters. Finally, a morphological study on the Cu(i)-iodine bearing 2-amino-5-nitropyridine nanofibres has confirmed their reversible molecular recognition ability towards acetic acid vapours
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Google Scholar:Conesa-Egea, Javier
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Hassanein, Khaled
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Muñoz, Marta
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Zamora Abanades, Félix Juan
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Amo Ochoa, María Pilar
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