dc.contributor.author | Conesa-Egea, Javier | |
dc.contributor.author | Hassanein, Khaled | |
dc.contributor.author | Muñoz, Marta | |
dc.contributor.author | Zamora Abanades, Félix Juan | |
dc.contributor.author | Amo Ochoa, María Pilar | |
dc.contributor.other | UAM. Departamento de Química Inorgánica | es_ES |
dc.date.accessioned | 2019-10-10T12:38:59Z | |
dc.date.available | 2019-10-10T12:38:59Z | |
dc.date.issued | 2018-04-28 | |
dc.identifier.citation | Dalton Transactions 47.16 (2018): 5607-5613 | en_US |
dc.identifier.issn | 1477-9226 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10486/688831 | |
dc.description.abstract | We report on the direct formation of 1D nanostructures of two coordination polymers based on copper(i)-iodine double chains decorated with ethyl isonicotinate or 2-amino-5-nitropyridine as terminal ligands. The use of different reaction conditions, e.g. energy of the formation process, solvents, and/or concentration of reactants, has allowed the control of the size of the fibres and ribbons directly formed in this process going from micron- to submicron- up to nano-size. We show experiments that direct the formation of materials kinetically versus thermodynamically controlled, adjusting simple experimental parameters. Finally, a morphological study on the Cu(i)-iodine bearing 2-amino-5-nitropyridine nanofibres has confirmed their reversible molecular recognition ability towards acetic acid vapours | en_US |
dc.description.sponsorship | We are grateful for financial support from the Spanish Ministerio de Economía y Competitividad (MAT2013-46502-C2-2P, MAT2016-75883-C2-2-P, BES-2015-071534) and also to the scientific computing center (CCC) of the Autónoma University of Madrid for their time | en_US |
dc.format.extent | 8 pag. | en_US |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Royal Society of Chemistry | en_US |
dc.relation.ispartof | Dalton Transactions | en_US |
dc.rights | © 2018 The Royal Society of Chemistry | en_US |
dc.subject.other | Copper compounds | en_US |
dc.subject.other | Polymers | en_US |
dc.subject.other | Nanostructures | en_US |
dc.subject.other | Ligands | en_US |
dc.subject.other | Iodine | en_US |
dc.title | Fast and efficient direct formation of size-controlled nanostructures of coordination polymers based on copper(i)-iodine bearing functional pyridine terminal ligands | en_US |
dc.type | article | en |
dc.subject.eciencia | Química | es_ES |
dc.date.embargoend | 2019-04-28 | |
dc.relation.publisherversion | https://doi.org/10.1039/C8DT00083B | es_ES |
dc.identifier.doi | 10.1039/C8DT00083B | es_ES |
dc.identifier.publicationfirstpage | 5607 | es_ES |
dc.identifier.publicationissue | 16 | es_ES |
dc.identifier.publicationlastpage | 5613 | es_ES |
dc.identifier.publicationvolume | 47 | es_ES |
dc.relation.projectID | Gobierno de España. MAT2016-75883-C2-2-P | es_ES |
dc.relation.projectID | Gobierno de España. BES-2015-071534 | es_ES |
dc.relation.projectID | Gobierno de España. MAT2013-46502-C2-2-P | es_ES |
dc.type.version | info:eu-repo/semantics/acceptedVersion | en |
dc.rights.accessRights | openAccess | en |
dc.authorUAM | Conesa Egea, Javier (271764) | |
dc.authorUAM | Hassanein Sayed Ahmed, Khaled (264971) | |
dc.authorUAM | Zamora Abanades, Félix Juan (258846) | |
dc.authorUAM | Amo Ochoa, María Pilar (261554) | |
dc.facultadUAM | Facultad de Ciencias | |
dc.institutoUAM | Centro de Investigación en Física de la Materia Condensada (IFIMAC) | |
dc.institutoUAM | Instituto de Investigación Avanzada en Ciencias Químicas (IAdChem) | |