Fast and efficient direct formation of size-controlled nanostructures of coordination polymers based on copper(i)-iodine bearing functional pyridine terminal ligands

Biblos-e Archivo/Manakin Repository

Show simple item record

dc.contributor.author Conesa-Egea, Javier
dc.contributor.author Hassanein, Khaled
dc.contributor.author Muñoz, Marta
dc.contributor.author Zamora, Félix
dc.contributor.author Amo-Ochoa, Pilar
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2019-10-10T12:38:59Z
dc.date.available 2019-10-10T12:38:59Z
dc.date.issued 2018-04-28
dc.identifier.citation Dalton Transactions 47.16 (2018): 5607-5613 en_US
dc.identifier.issn 1477-9226 es_ES
dc.identifier.uri http://hdl.handle.net/10486/688831
dc.description.abstract We report on the direct formation of 1D nanostructures of two coordination polymers based on copper(i)-iodine double chains decorated with ethyl isonicotinate or 2-amino-5-nitropyridine as terminal ligands. The use of different reaction conditions, e.g. energy of the formation process, solvents, and/or concentration of reactants, has allowed the control of the size of the fibres and ribbons directly formed in this process going from micron- to submicron- up to nano-size. We show experiments that direct the formation of materials kinetically versus thermodynamically controlled, adjusting simple experimental parameters. Finally, a morphological study on the Cu(i)-iodine bearing 2-amino-5-nitropyridine nanofibres has confirmed their reversible molecular recognition ability towards acetic acid vapours en_US
dc.description.sponsorship We are grateful for financial support from the Spanish Ministerio de Economía y Competitividad (MAT2013-46502-C2-2P, MAT2016-75883-C2-2-P, BES-2015-071534) and also to the scientific computing center (CCC) of the Autónoma University of Madrid for their time en_US
dc.format.extent 8 pag. en_US
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher Royal Society of Chemistry en_US
dc.relation.ispartof Dalton Transactions en_US
dc.rights © 2018 The Royal Society of Chemistry en_US
dc.subject.other Copper compounds en_US
dc.subject.other Polymers en_US
dc.subject.other Nanostructures en_US
dc.subject.other Ligands en_US
dc.subject.other Iodine en_US
dc.title Fast and efficient direct formation of size-controlled nanostructures of coordination polymers based on copper(i)-iodine bearing functional pyridine terminal ligands en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.date.embargoend 2019-04-28
dc.relation.publisherversion https://doi.org/10.1039/C8DT00083B es_ES
dc.identifier.doi 10.1039/C8DT00083B es_ES
dc.identifier.publicationfirstpage 5607 es_ES
dc.identifier.publicationissue 16 es_ES
dc.identifier.publicationlastpage 5613 es_ES
dc.identifier.publicationvolume 47 es_ES
dc.relation.projectID Gobierno de España. MAT2016-75883-C2-2-P es_ES
dc.relation.projectID Gobierno de España. BES-2015-071534 es_ES
dc.relation.projectID Gobierno de España. MAT2013-46502-C2-2-P es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.accessRights openAccess en
dc.authorUAM Conesa Egea, Javier (271764)
dc.authorUAM Hassanein Sayed Ahmed, Khaled (264971)
dc.authorUAM Zamora Abanades, Félix Juan (258846)
dc.authorUAM Amo Ochoa, María Pilar (261554)


Files in this item

Thumbnail
Thumbnail

This item appears in the following Collection(s)

Show simple item record