dc.contributor.author | Castillo, Oscar | |
dc.contributor.author | Delgado, Esther | |
dc.contributor.author | Gómez-García, Carlos J. | |
dc.contributor.author | Hernández, Diego | |
dc.contributor.author | Hernández, Elisa | |
dc.contributor.author | Martín, Avelino | |
dc.contributor.author | Martínez, José I. | |
dc.contributor.author | Zamora Abanades, Félix Juan | |
dc.contributor.other | UAM. Departamento de Química Inorgánica | es_ES |
dc.date.accessioned | 2019-10-17T10:45:29Z | |
dc.date.available | 2019-10-17T10:45:29Z | |
dc.date.issued | 2017-10-02 | |
dc.identifier.citation | Inorganic Chemistry 56.19 (2017): 11810-11818 | es_ES |
dc.identifier.issn | 1520-510X (online) | en_US |
dc.identifier.issn | 0020-1669 (print) | en_US |
dc.identifier.uri | http://hdl.handle.net/10486/688871 | |
dc.description | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775 | en_US |
dc.description.abstract | The use of theoretical calculations has allowed us to predict the coordination behavior of dithiolene [M(SC6H4S)2]2- (M = Ni, Pd, Pt) entities, giving rise to the first organometallic polymers {[K2(μ-H2O)2][Ni(SC6H4S)2]}n and {[K2(μ-H2O)2(thf)]2[K2(μ-H2O)2(thf)2][Pd3(SC6H4S)6]}n by one-pot reactions of the corresponding d10 metal salts, 1,2-benzenedithiolene, and KOH. The polymers are based on σ,π interactions between potassium atoms and [M(SC6H4S)2]2- (M = Ni, Pd) entities. In contrast, only σ interactions are observed when the analogous platinum derivative is used instead, yielding the coordination polymer {[K2(μ-thf)2][Pt(SC6H4S)2]}n | en_US |
dc.description.sponsorship | This work was supported in part by the MICINN (grants MAT2016-77608-C3-1-P and MAT2016-75883-C2-1-P), Generalitat Valenciana (PrometeoII/2014/076), and ISIC. J.I.M.
acknowledges financial support by the “Ramon y Cajal ́ ” Program of MINECO (RYC-2015-17730) | en_US |
dc.format.extent | 30 pag. | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | American Chemical Society | en_US |
dc.relation.ispartof | Inorganic Chemistry | en_US |
dc.rights | © 2017 American Chemical Society | en_US |
dc.subject.other | Coordination polymers | en_US |
dc.subject.other | Metal-dithiolene polymers | en_US |
dc.subject.other | Coordination compounds | en_US |
dc.subject.other | First-principles calculations | en_US |
dc.title | Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations | en_US |
dc.type | article | en |
dc.subject.eciencia | Química | es_ES |
dc.date.embargoend | 2018-10-02 | |
dc.relation.publisherversion | https://doi.org/10.1021/acs.inorgchem.7b01775 | es_ES |
dc.identifier.doi | 10.1021/acs.inorgchem.7b01775 | es_ES |
dc.identifier.publicationfirstpage | 11810 | es_ES |
dc.identifier.publicationissue | 19 | es_ES |
dc.identifier.publicationlastpage | 11818 | es_ES |
dc.identifier.publicationvolume | 56 | es_ES |
dc.relation.projectID | Gobierno de España. MAT2016-77608-C3-1-P | es_ES |
dc.relation.projectID | Gobierno de España. MAT2016-75883-C2-1-P | es_ES |
dc.relation.projectID | Gobierno de España. RYC-2015-17730 | es_ES |
dc.type.version | info:eu-repo/semantics/acceptedVersion | en |
dc.rights.accessRights | openAccess | en |
dc.authorUAM | Delgado Laita, Esther (259693) | |
dc.authorUAM | Zamora Abanades, Félix Juan (258846) | |
dc.facultadUAM | Facultad de Ciencias | |
dc.institutoUAM | Instituto de Investigación Avanzada en Ciencias Químicas (IAdChem) | |