Spray drying for making covalent chemistry II: Synthesis of covalent-organic framework superstructures and related composites

Garzón-Tovar, Luis; Avci-Camur, Ceren; Rodríguez-San-Miguel, David; Imaz, Inhar; Zamora, Félix; Maspoch, Daniel

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Spray drying for making covalent chemistry II: Synthesis of covalent-organic framework superstructures and related composites

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Title: Spray drying for making covalent chemistry II: Synthesis of covalent-organic framework superstructures and related composites

Author: Garzón-Tovar, Luis; Avci-Camur, Ceren; Rodríguez-San-Miguel, David; Imaz, Inhar; Zamora, Félix; Maspoch, Daniel

Entity: UAM. Departamento de Química Inorgánica

UAM Author: Rodríguez San Miguel, David

; Zamora Abanades, Félix Juan

Publisher: Royal Society of Chemistry

Date: 2017-10-21

Citation: Chemical Communications 53.82 (2017): 11372-11375

ISSN: 1364-548X (online); 1359-7345 (print)

DOI: 10.1039/C7CC07052G

Funded by: This work was supported by the Spanish MINECO (project PN MAT2015-65354-C2-1-R), the Catalan AGAUR (project 2014 SGR 80), and the ERC under the EU FP7 (ERC-Co 615954). It was also funded by the CERCA Programme/Generalitat de Catalunya. ICN2 acknowledges the support of the Spanish MINECO through the Severo Ochoa Centers of Excellence Program under Grant SEV-2013-0295

Project: Gobierno de España. MAT2015-65354-C2-1-R; Gobierno de España. SEV-2013-0295; info:eu-repo/grantAgreement/EC/FP7/615954

Editor's Version: https://doi.org/10.1039/C7CC07052G

Subjects: Frameworks COFs; Coordination compounds; Nanocrystal; Química

URI: http://hdl.handle.net/10486/688890

Abstract:

Here we report a method that combines the spray-drying technique with a dynamic covalent chemistry process to synthesize zero-dimensional, spherical and microscale superstructures made from the assembly of imine-based COF nanocrystals. This methodology also enables the integration of other functional materials into these superstructures forming COF-based composites.

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