3D Printing of a Thermo- and Solvatochromic Composite Material Based on a Cu(II)–Thymine Coordination Polymer with Moisture Sensing Capabilities

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dc.contributor.author Maldonado, Noelia
dc.contributor.author Vegas, Verónica G.
dc.contributor.author Halevi, Oded
dc.contributor.author Martínez, Jose Ignacio
dc.contributor.author Lee, Pooi See
dc.contributor.author Magdassi, Shlomo
dc.contributor.author Wharmby, Michael T.
dc.contributor.author Platero-Prats, Ana E.
dc.contributor.author Moreno, Consuelo
dc.contributor.author Zamora, Félix
dc.contributor.author Amo-Ochoa, Pilar
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2019-11-25T11:43:29Z
dc.date.available 2019-11-25T11:43:29Z
dc.date.issued 2019-04-11
dc.identifier.citation Advanced Functional Materials 29.15 (2019): 1808424 en_US
dc.identifier.issn 1616-301X (print) en_US
dc.identifier.issn 1616-3028 (online) en_US
dc.identifier.uri http://hdl.handle.net/10486/689318
dc.description This is the peer reviewed version of the following article: Advanced Functional Materials 29.15 (2019): 1808424, which has been published in final form at https://doi.org/10.1002/adfm.201808424. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions en_US
dc.description.abstract This work presents the fabrication of 3D-printed composite objects based on copper(II) 1D coordination polymer (CP1) decorated with thymine along its chains with potential utility as an environmental humidity sensor and as a water sensor in organic solvents. This new composite object has a remarkable sensitivity, ranging from 0.3% to 4% of water in organic solvents. The sensing capacity is related to the structural transformation due to the loss of water molecules that CP1 undergoes with temperature or by solvent molecules' competition, which induces significant change in color simultaneously. The CP1 and 3D printed materials are stable in air over 1 year and also at biological pHs (5–7), therefore suggesting potential applications as robust colorimetric sensors. These results open the door to generate a family of new 3D printed materials based on the integration of multifunctional coordination polymers with organic polymers en_US
dc.description.sponsorship N.M. and V.G.V. contributed equally to this work. The authors thank financial support from the Spanish Ministerio de Economía y Competitividad (MAT2016‐77608‐C3‐1‐P, MAT2016‐75883‐C2‐2‐P) and the National Research Foundation, Prime Minister's Office, Singapore, under its Campus for Research Excellence and Technological Enterprise (CREATE) programme. O.H. acknowledges the support for Ph.D. students from The Hebrew University of Jerusalem. J.I.M. acknowledges the financial support by the “Ramón y Cajal” Program of MINECO (Grant RYC‐2015‐17730) and the EU via the ERC‐Synergy Program (Grant ERC‐2013‐SYG‐610256 NANOCOSMOS). A.E.P.‐P. acknowledges a TALENTO grant (2017‐T1/IND5148) from Comunidad de Madrid. The authors acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Parts of this research were carried out at beamline P02.1 PETRA III under the proposal I‐20170717 EC. V.G.V. thanks to the Ministry of Education, Youth and Sports, the Madrid Community and the European Social Fund. The authors thank Deseada Diaz Barrero, from Autonoma University of Madrid, Applied Physics Department, for the study of diffuse reflectance of the compound presented here en_US
dc.format.extent 36 pag. en_US
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher Wiley-VCH Verlag en_US
dc.relation.ispartof Advanced Functional Materials en_US
dc.rights © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim en_US
dc.subject.other 3D printing en_US
dc.subject.other Solvato-thermochromic, water detection en_US
dc.subject.other Sensing en_US
dc.subject.other Coordination polymers en_US
dc.title 3D Printing of a Thermo- and Solvatochromic Composite Material Based on a Cu(II)–Thymine Coordination Polymer with Moisture Sensing Capabilities en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.date.embargoend 2020-04-11
dc.relation.publisherversion https://doi.org/10.1002/adfm.201808424 es_ES
dc.identifier.doi 10.1002/adfm.201808424 es_ES
dc.identifier.publicationfirstpage 1808424-1 es_ES
dc.identifier.publicationissue 15 es_ES
dc.identifier.publicationlastpage 1808424-11 es_ES
dc.identifier.publicationvolume 29 es_ES
dc.relation.projectID Gobierno de España. MAT2016‐77608‐C3‐1‐P es_ES
dc.relation.projectID Gobierno de España. MAT2016‐75883‐C2‐2‐P es_ES
dc.relation.projectID Gobierno de España. RYC‐2015‐17730 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/610256 en_US
dc.relation.projectID Comunidad de Madrid. S2017 es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.accessRights embargoedAccess en
dc.authorUAM García Vegas, Verónica (314148)
dc.authorUAM Platero Prats, Ana Eva (281277)
dc.authorUAM Moreno Barahona, Consuelo (259205)
dc.authorUAM Zamora Abanades, Félix Juan (258846)
dc.authorUAM Amo Ochoa, María Pilar (261554)

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