dc.contributor.author | Conesa-Egea, Javier | |
dc.contributor.author | Moreno-Vázquez, Alberto | |
dc.contributor.author | Fernández-Moreira, Vanesa | |
dc.contributor.author | Ballesteros, Yolanda | |
dc.contributor.author | Castellanos, Milagros | |
dc.contributor.author | Zamora Abanades, Félix Juan | |
dc.contributor.author | Amo Ochoa, María Pilar | |
dc.contributor.other | UAM. Departamento de Química Inorgánica | es_ES |
dc.date.accessioned | 2020-01-09T11:18:13Z | |
dc.date.available | 2020-01-09T11:18:13Z | |
dc.date.issued | 2019-06-15 | |
dc.identifier.citation | Polymers 11.6 (2019): 1047 | es_ES |
dc.identifier.issn | 2073-4360 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10486/689692 | |
dc.description.abstract | Herein is presented the preparation and characterization of a composite material obtained by the combination of nanosheets of a coordination polymer (CP) based on the copper(I)-I double chain with response to temperature and pressure with polylactic acid (PLA) as biodegradable organic matrix. The new films of composite materials are generated using a simple and low-cost method and can be created with long lateral dimensions and thicknesses ranging from a few microns to a few nanometers. Studies show that the new material maintains the optical response versus the temperature, while the elasticity and flexibility of the PLA totally quenches the response to pressure previously observed for the CP. This new material can act as a reversible sensor at low temperatures, thanks to the flexibility of the copper(I)-iodine chain that conforms the CP. The addition of CP to the PLA matrix reduces the elastic modulus and ultimate elongation of the organic matrix, although it does not reduce its tensile strength | en_US |
dc.description.sponsorship | This article has been funded by the Spanish Ministerio de Economía y Competitividad (and the current Ministerio de Ciencia, Innovación y Universidades) (MAT2016-77608-C3-1-P, MAT2016-75883-C2-2-P, MAT2016-75586-C4-4-P, CTQ2016-75816-C2-1P). J.C.-E. acknowledges the financial support by the “FPI-MINECO” Program of MINECO (Grant BES-2015-071534) | en_US |
dc.format.extent | 14 pag. | es_ES |
dc.format.mimetype | application/pdf | es_ES |
dc.language.iso | eng | en |
dc.publisher | MDPI | en_US |
dc.relation.ispartof | Polymers | en_US |
dc.rights | © 2019 by the authors. | en_US |
dc.subject.other | Coordination polymers | en_US |
dc.subject.other | Flexible composites | en_US |
dc.subject.other | Functional composites | en_US |
dc.subject.other | Smart materials | en_US |
dc.subject.other | Stimuli-responsive materials | en_US |
dc.title | Micro and nano smart composite films based on copper-iodine coordination polymer as thermochromic biocompatible sensors | en_US |
dc.type | article | en |
dc.subject.eciencia | Química | es_ES |
dc.relation.publisherversion | https://doi.org/10.3390/polym11061047 | es_ES |
dc.identifier.doi | 10.3390/polym11061047 | es_ES |
dc.identifier.publicationfirstpage | 1047-1 | es_ES |
dc.identifier.publicationissue | 6 | es_ES |
dc.identifier.publicationlastpage | 1047-14 | es_ES |
dc.identifier.publicationvolume | 11 | es_ES |
dc.relation.projectID | Gobierno de España. MAT2016-77608-C3-1-P | es_ES |
dc.relation.projectID | Gobierno de España. MAT2016-75883-C2-2-P | es_ES |
dc.relation.projectID | Gobierno de España. MAT2016-75586-C4-4-P | es_ES |
dc.relation.projectID | Gobierno de España. CTQ2016-75816-C2-1P | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.rights.cc | Reconocimiento | es_ES |
dc.rights.accessRights | openAccess | en |
dc.authorUAM | Conesa Egea, Javier (271764) | |
dc.authorUAM | Zamora Abanades, Félix Juan (258846) | |
dc.authorUAM | Amo Ochoa, María Pilar (261554) | |
dc.facultadUAM | Facultad de Ciencias | |
dc.institutoUAM | Centro de Investigación en Física de la Materia Condensada (IFIMAC) | |
dc.institutoUAM | Instituto de Investigación Avanzada en Ciencias Químicas (IAdChem) | |