Asymmetric trifluoromethylthiolation of azlactones under chiral phase transfer catalysis
Entity
UAM. Departamento de Química; UAM. Departamento de Química OrgánicaPublisher
Royal Society of ChemistryDate
2020-04-21Citation
10.1039/D0OB00476F
Organic & Biomolecular Chemistry 18.15 (2020): 2914-2920
ISSN
1477-0520 (print); 1477-0539 (online)DOI
10.1039/D0OB00476FFunded by
We are grateful to the Spanish Government (RTI2018-095038-B-I00, CTQ, CTQ2016-76061-P), “Comunidad de Madrid” and European Structural Funds (S2018/NMT-4367)Project
Gobierno de España. RTI2018-095038-B-I00; Gobierno de España. CTQ2016-76061-P; Comunidad de Madrid. S2018/NMT-4367Editor's Version
https://doi.org/10.1039/D0OB00476FSubjects
Aryl groups; Electron; Catalysis; QuímicaRights
© The Royal Society of Chemistry 2020Abstract
The first enantioselective method for the installation of the SCF3 group at the C-4 position of azlactones is described in the present communication under quinidinium phase transfer catalysis. The higher performance of substrates containing electron-rich 2-aryl groups at the azlactone was rationalized using DFT calculations
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Google Scholar:Sicignano, Marina
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Rodríguez, Ricardo I.
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Capaccio, Vito
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Fabio, Borello
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Cano, Rafael
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De Riccardis, Francesco
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Bernardi, Luca
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Díaz-Tendero Victoria, Sergio
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Della Sala, Giorgio
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Alemán Lara, José Julián
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