A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence

Abstract

The simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)]n (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence.