dc.contributor.author | Martinez-martin, Paloma | |
dc.contributor.author | Perles, Josefina | |
dc.contributor.author | Rodríguez Ubis, J. Carlos | |
dc.contributor.other | UAM. Departamento de Química Orgánica | es |
dc.date.accessioned | 2020-06-23T08:39:04Z | |
dc.date.available | 2020-06-23T08:39:04Z | |
dc.date.issued | 2020-02-01 | |
dc.identifier.citation | Crystals 10.2 (2020): 69 | en_US |
dc.identifier.issn | 2073-4352 | |
dc.identifier.uri | http://hdl.handle.net/10486/691359 | |
dc.description.abstract | Luminescent mixed lanthanide metal−organic framwork (MOF) materials have been prepared from two polyheterocyclic diacid ligands, 2,6-bis(3-carboxy-1-pyrazolyl)pyridine and 2,6- bis(4-carboxy-1-pyrazolyl)pyridine. The crystal structures of the two organic molecules are presented together with the structures for the MOFs obtained by hydrothermal synthesis either with Yb(III) or mixed Tb(III)/Yb(III) ions. Different coordination architectures result from each ligand, revealing also important differences between the lanthanides. The mixed lanthanide metal−organic frameworks also present diverse luminescent behavior; in the case of 2,6-bis(4-carboxy-1- pyrazolyl)pyridine, where no coordinated water is present in the metal environment, Tb(III) and Yb(III) characteristic emission is observed by excitation of the bispyrazolylpyridine chromophore | en_US |
dc.description.sponsorship | The research leading to these results has received funding from ERCROS S.A. (Aranjuez, Spain) | en_US |
dc.format.extent | 15 pag. | en_US |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | M D P I AG | en_US |
dc.relation.ispartof | Crystals | en_US |
dc.rights | © 2020 by the authors | en_US |
dc.subject.other | Coordination polymers | en_US |
dc.subject.other | Energy transfer | en_US |
dc.subject.other | Lanthanide luminescence | en_US |
dc.subject.other | LnMOF | en_US |
dc.subject.other | Tb(III)/Yb(III) ions | en_US |
dc.subject.other | Topology | en_US |
dc.title | Crystal structure dependence of the energy transfer from tb(III) to yb(III) in metal–organic frameworks based in bispyrazolylpyridines | en_US |
dc.type | article | en |
dc.subject.eciencia | Química | es |
dc.relation.publisherversion | https://doi.org/10.3390/cryst10020069 | |
dc.identifier.doi | 10.3390/cryst10020069 | |
dc.identifier.publicationfirstpage | 69-1 | |
dc.identifier.publicationissue | 2 | |
dc.identifier.publicationlastpage | 69-15 | |
dc.identifier.publicationvolume | 10 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.rights.cc | Reconocimiento | es_ES |
dc.rights.accessRights | openAccess | en |
dc.authorUAM | Rodríguez Ubis, J. Carlos (259359) | |
dc.facultadUAM | Facultad de Ciencias | |