Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via RhIII-catalyzed cascade oxidative alkenylation/annulation of picolinamides
Entity
UAM. Departamento de Química OrgánicaPublisher
The Royal Society of ChemistryDate
2014-06-11Citation
10.1039/c4cc02322f
Chemical Communications 50.46 (2014): 6105-6107
ISSN
1359-7345 (print); 1364-548X (online)DOI
10.1039/c4cc02322fFunded by
We thank Spanish Government (MINECO, CTQ2012-35790) and Madrid regional government (AVANCAT, S2009/PPQ-1634) for financial support. N.R. thanks the MICINN for a Ramón y Cajal contract and the Marie Curie Foundation (CIG: CHAAS- 304085)Project
Comunidad de Madrid. S2009/PPQ-1634/ AVANCAT; info:eu-repo/grantAgreement/EC/FP7/304085; Gobierno de España. CTQ2012-35790Editor's Version
http://dx.doi.org/10.1039/C4CC02322FSubjects
Picolinamide; Pyridine derivative; Pyrrolo[3,4 b]pyridin 7 one derivative; Rhodium; Unclassified drug; Alkene; QuímicaRights
© the Partner Organisations 2014; © The Royal Society of Chemistry 2014Abstract
A practical RhIII-catalyzed cascade olefination/annulation of picolinamides leading to pyrrolo[3,4-b]pyridines has been developed. The reaction shows wide scope, complete regiocontrol and excellent stereoselectivity
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Google Scholar:Martínez, Ángel Manu
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Rodríguez Garrido, Nuria
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Gómez Arrayas, Ramón Jesús
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Carretero Gonzálvez, Juan Carlos
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