Quantum control of isomerization by robust navigation in the energy spectrum
Entidad
UAM. Departamento de QuímicaEditor
American Institute of Physics Publising LLCFecha de edición
2015-12-07Cita
10.1063/1.4936424
Journal of Chemical Physics 143.21 (2015): 214305
ISSN
0021-9606 (print); 1089-7690 (online)DOI
10.1063/1.4936424Financiado por
This research was supported by the Ministry of Economy and Competitiveness-Spain under Contract Nos. MTM2012- 39101 and ICMAT Severo Ochoa SEV-2001-0087, ANPCyTArgentina (PICT-1187), and CONICET-Argentina (PIP- 00273)Proyecto
Gobierno de España. MTM2012- 39101; Gobierno de España. SEV-2001-0087Versión del editor
http://dx.doi.org/10.1063/1.4936424Materias
Control theory; Electric fields; Hamiltonians; Isomerization; QuímicaDerechos
© 2015 AIP Publishing LLCResumen
In this paper, we present a detailed study on the application of the quantum control technique of navigation in the energy spectrum to chemical isomerization processes, namely, CN-Li → ←Li-CN. This technique is based on the controlled time variation of a Hamiltonian parameter, an external uniform electric field in our case. The main result of our work establishes that the navigation involved in the method is robust, in the sense that quite sizable deviations from a pre-established control parameter time profile can be introduced and still get good final results. This is specially relevant thinking of a experimental implementation of the method
Lista de ficheros
Google Scholar:Murgida, G.E.
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Arranz, F. J.
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Borondo, Florentino
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