Comparative studies of oxidation processes on Group 10 Metals Dithiolene Derivatives in the formation of coordination polymers
Entity
UAM. Departamento de Química Inorgánica; UAM. Departamento de Química Física AplicadaPublisher
American Chemical SocietyDate
2018-03-14Citation
10.1021/acs.cgd.8b00103
Crystal Growth and Design 18.4 (2018): 2486-2494
ISSN
1528-7483 (print); 1528-7505 (online)DOI
10.1021/acs.cgd.8b00103Funded by
This work was supported in part by MICINN (grants MAT2016-77608-C3-1-P, MAT2016-75883-C2-1-P, CTQ2013-44625-R and and CTQ2017-87201-P) and Generalitat Valenciana (PrometeoII/2014/076)Project
Gobierno de España. MAT2016-77608-C3-1-P; Gobierno de España. MAT2016-75883-C2-1-P; Gobierno de España. CTQ2013-44625-R; Gobierno de España. CTQ2017-87201-PEditor's Version
http://doi.org/10.1021/acs.cgd.8b00103Subjects
Coordination polymers; Group 10 metal dithiolene compounds; Group 10 metal dithiolene Ion-Pairs; Dianionic tetranickel dithiolene cluster; Física; QuímicaNote
This document is the Accepted Manuscript Version of a Published Work that appeared in final form in "Crystal Growth and Design", copyright © 2018 American Chemical Society after peer review and techical editing by publisher. To access the final and published work see "Comparative Studies of Oxidation Processes on Group 10 Metals Dithiolene Derivatives in the Formation of Coordination Polymers Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, and Félix Zamora Crystal Growth & Design 2018 18 (4), 2486-2494Rights
© 2018 American Chemical SocietyAbstract
Air oxidation of the dithiolene derivatives {[K2(μ-H2O)2(μ-thf)(thf)2][Ni(SC6H2Cl2S)2]}n and {[K2(μ-H2O)2(thf)6][Pt(SC6H2Cl2S)2]}n yielded the ion-pair compounds [K(thf)6][M(SC6H2Cl2S)2] [M = Ni or Pt], while no reaction was observed for the case of {[K2(μ-H2O)2(μ-thf)(thf)2][Pd(SC6H2Cl2S)2]}n. Cyclic voltammetric studies have been used to rationalize this different behavior. Additionally, the new coordination polymers {[K2(thf)8][Ni4(SC6H4S)6]}n, {[K4(thf)4(H2O)2.28][Pd(O2SC6H4S)1.36(OSC6H4S)0.64]2}n, {[K2(H2O)4][Pd(O2SC6H4S)2][Pd(O2SC6H4S)(SC6H4S)]}n, and {[K4(thf)4(H2O)2.24][Pt(O2SC6H4S)1.38(OSC6H4S)0.62]2}n have been obtained using a similar synthetic strategy, i.e., oxidation reactions of group 10 metals dithiolene derivatives bearing (SC6H4S)2– ligands
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Google Scholar:Castillo, Óscar
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Delgado, Esther
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Gómez-García, Carlos J.
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Hernández, Diego
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Hernández, Elisa
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Herrasti González, Pilar
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Martín, Avelino
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Zamora Abanades, Félix Juan
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