Unprecedented layered coordination polymers of dithiolene group 10 metals: Magnetic and electrical properties
Entity
UAM. Departamento de Química InorgánicaPublisher
Royal Society of ChemistryDate
2016-04-21Citation
10.1039/C6DT00464D
Dalton Transactions 45.15 (2016): 6696-6701
ISSN
1477-9226 (print); 1477-9234 (online)DOI
10.1039/C6DT00464DFunded by
We thank financial support from MICINN (MAT2013-46753-C2-1-P, CTQ2014-52758-P and MAT2014-56143-R) and Generalitat Valenciana (PrometeoII/2014/076)Project
Gobierno de España. MAT2013-46753-C2-1-P; Gobierno de España. CTQ2014-52758-P; Gobierno de España. MAT2014-56143-REditor's Version
https://doi.org/10.1039/C6DT00464DSubjects
Polymers; Chlorine compounds; Complex networks; Complexation; Coordination reactions; Nickel; Palladium compounds; Platinum; X ray analysis; QuímicaRights
© The Royal Society of Chemistry 2016.Abstract
One-pot reactions between Ni(ii), Pd(ii) or Pt(ii) salts and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in KOH medium under argon lead to a series of bis-dithiolene coordination polymers. X-ray analysis shows the presence of a common square planar complex [M(SC6H2Cl2S)2]2- linked to potassium cations forming either a two-dimensional coordination polymer network for {[K2(μ-H2O)2(μ-thf)(thf)2][M(SC6H2Cl2S)2]}n [M = Ni (1) and Pd (2)] or a one-dimensional coordination polymer for {[K2(μ-H2O)2(thf)6][Pt(SC6H2Cl2S)2]}n (3). In 3 the coordination environment of the potassium ions may slightly change leading to the two-dimensional coordination polymer {[K2(μ-H2O)(μ-thf)2][Pt(SC6H2Cl2S)2]}n (4) that crystallizes together with 3. The physical characterization of compounds 1-3 show similar trends, they are diamagnetic and behave as semiconductors
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Google Scholar:Delgado, Esther
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Gómez-García, Carlos J.
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Hernández, Diego
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Hernández, Elisa
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Martín, Avelino
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Zamora Abanades, Félix Juan
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