Predesigned covalent organic frameworks as effective platforms for Pd(II) coordination enabling cross-coupling reactions under sustainable conditions
Entity
UAM. Departamento de Química Inorgánica; UAM. Departamento de Química OrgánicaPublisher
WileyDate
2021-12-29Citation
10.1002/adsu.202100409
Advanced Sustainable Systems 6.3 (2022): 2100409
ISSN
2366-7486DOI
10.1002/adsu.202100409Project
Gobierno de España. RTI2018-095038-B-I00; Gobierno de España. PID2019-110637RB-I00; Comunidad de Madrid. S2018/NMT-4367/FotoArt; Comunidad de Madrid. Y2020/NMT-6469/FOTOSURF; info:eu-repo/grantAgreement/EC/H2020/647550Editor's Version
https://doi.org/10.1002/adsu.202100409Subjects
Covalent organic frameworks; Catalysis; Phenanthroline; X-ray photoelectron spectroscopy; C-C cross-coupling reactions; QuímicaRights
© 2021 The AuthorsAbstract
The phenanthroline unit in an imine-based covalent organic framework (Phen-COF) offers a robust coordination site for Pd(OAc)2 centers. Coordination of palladium centers is demonstrated by a variety of techniques, including X-ray photoelectron spectroscopy and total X-ray fluorescence. The stable phenanthroline-Pd(II) coordination avoids leaching of metal centers to the reaction medium, where deactivation processes through nanoparticle formation limits the catalytic activities observed for homogeneous systems. Thus, because of isolation and immobilization of catalytic sites in the Pd@Phen-COF the performance of material, the catalytic outputs are dramatically increased with respect to the performance observed for analogous molecular catalysts. This concept is applied in this work to C-C cross-coupling reactions under mild and environmentally benign conditions. The activities found for Suzuki-Miyaura and Mizoroki-Heck reactions allow thousands of turnover numbers in the transformation of a wide scope of precursors with a high degree of recyclability. The results reported in this work contribute to the design of greener protocols for transformations that have a crucial role in the industrial synthesis of high-added value fine chemicals
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Google Scholar:López Magano, Alberto
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Mas Ballesté, Rubén
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Alemán Lara, José Julián
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