Identification of the invariant manifolds of the LiCN molecule using Lagrangian descriptors
Entidad
UAM. Departamento de QuímicaEditor
American Physical SocietyFecha de edición
2021-10-20Cita
10.1103/PhysRevE.104.044210
Physical Review E 104.4 (2021): 044210
ISSN
2470-0045 (print); 2470-0053 (online)DOI
10.1103/PhysRevE.104.044210Proyecto
Gobierno de España. PGC2018-093854-B-I00; info:eu-repo/grantAgreement/EC/H2020/734557/EU//TraX; Gobierno de España. CEX2019-000904-SVersión del editor
https://doi.org/10.1103/PhysRevE.104.044210Materias
Isomerization; Lagrange Multipliers; Lithium Compounds; Molecular Physics; Nitrogen Compounds; Potential Energy; Potential Energy Surfaces; Quantum Chemistry; QuímicaDerechos
© 2021 American Physical SocietyResumen
In this paper, we apply Lagrangian descriptors to study the invariant manifolds that emerge from the top of two barriers existing in the LiCN --><-- LiNC isomerization reaction. We demonstrate that the integration times must be large enough compared with the characteristic stability exponents of the periodic orbit under study. The invariant manifolds manifest as singularities in the Lagrangian descriptors. Furthermore, we develop an equivalent potential energy surface with 2 degrees of freedom, which reproduces with a great accuracy previous results [F. Revuelta, R. M. Benito, and F. Borondo, Phys. Rev. E 99, 032221 (2019)]. This surface allows the use of an adiabatic approximation to develop a more simplified potential energy with solely 1 degree of freedom. The reduced dimensional model is still able to qualitatively describe the results observed with the original 2- degrees-of-freedom potential energy landscape. Likewise, it is also used to study in a more simple manner the influence on the Lagrangian descriptors of a bifurcation, where some of the previous invariant manifolds emerge, even before it takes place
Lista de ficheros
Google Scholar:Revuelta, F.
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Benito, R. M.
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Borondo, Florentino
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