Enantiospecific Synthesis of 1,3-Disubstituted Allenes from Propargylic Carbonates through a Borylation-1,2-Elimination Process
Entity
UAM. Departamento de Química OrgánicaPublisher
WileyDate
2023-11-12Citation
10.1002/adsc.202300813
Advanced Synthesis and Catalysis (2023): 1-7
ISSN
1615-4150 (print); 1615-4169 (online)DOI
10.1002/adsc.202300813Funded by
We thank MINECO (CTQ2016-78779-R) and MICINN (PID2019-107380GB I00) for financial supportProject
Gobierno de España. CTQ2016-78779; Gobierno de España. PID2019-107380GB-IEditor's Version
https://doi.org/10.1002/adsc.202300813Subjects
1,2-anti-elimination; Allenes; Boronates; Propargylic carbonates; TBAF; QuímicaRights
© 2023 The AuthorsAbstract
An array of enantioenriched vinyl boronates bearing an allylic carbonate moiety have been
prepared through selective hydroboration of propargyl carbonates. Treatment of these vinyl boronates
with TBAF in THF affords enantioenriched 1,3-
disubstituted allenes through a novel 1,2-anti elimination in good yields and high enantiospecificities
Files in this item
Google Scholar:Jarava Barrera, Carlos
-
Parra Sánchez, Alejandro
-
Quesada, Sergio
-
Orgaz Gordillo, Sergio
-
Fernández de la Pradilla, Roberto
-
Viso, Alma
-
Teresa Ojeda, Javier
-
Alonso Montero, María Inés
-
Tortosa Manzanares, Mariola
This item appears in the following Collection(s)
Related items
Showing items related by title, author, creator and subject.