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dc.contributor.authorMatesanz, Ana I.
dc.contributor.authorPastor, César J.
dc.contributor.authorSouza, Pilar
dc.contributor.otherUAM. Departamento de Química Inorgánicaes_ES
dc.date.accessioned2015-04-17T08:52:50Z
dc.date.available2015-04-17T08:52:50Z
dc.date.issued2007-12-18
dc.identifier.citationEuropean Journal of Inorganic Chemistry 34 (2007): 5433-5438en_US
dc.identifier.issn1434-1948 (print)es_ES
dc.identifier.issn1099-0682 (online)es_ES
dc.identifier.urihttp://hdl.handle.net/10486/665180
dc.descriptionThis is the peer reviewed version of the following article: European Journal of Inorganic Chemistry 34 (2007): 5433-5438, which has been published in final form at http://dx.doi.org/10.1002/ejic.200700619. This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for self-archivingen_US
dc.description.abstractThe new cyclic 5-ethoxy-4-ethyl-5,6-diphenyl-4,5-dihydro-2H-[1,2,4]- triazine-3-thione ligand (HTa3T-Et) has been obtained by an intramolecular cyclization reaction of α-diphenylethanedione bis(4- ethylthiosemicarbazone) (H2BbTSC-Et). The cyclization may be promoted either by hydroxylic solvents or by ZnII ions. Thus, the reaction of H2BbTSC-Et with ZnCl2 led to the formation of [Zn(HTa3T-Et)2Cl2] containing not the ligand H 2BbTSC-Et but the cyclic HTa3T-Et ligand that forms during the reaction. On the other hand, crystallization of H2BbTSC-Et from DMSO/EtOH produces a cocrystal containing the open-chain H2BbTSC-Et ligand together with the cyclic HTa3T-Et molecules, which are linked to a DMSO molecule by hydrogen bonds. However, reaction of the cocrystal with Pd II ions yields a planar tetracoordinate complex in which only the H2BbTSC-Et ligand, in the deprotonated form, is present. The preparation and molecular structures of these compounds are discusseden_US
dc.description.sponsorshipWe are grateful to Ministerio de Sanidad y Consumo, Instituto de Salud Carlos III (PI040354) of Spain for financial supporten_US
dc.format.extent6 pag.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherWiley-VCH Verlag GmbH & Co. KGaAen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.rights© Wiley-VCH Verlag GmbH & Co. KGaA, 2007en_US
dc.subject.otherCocrystalsen_US
dc.subject.otherPalladiumd(II)es_ES
dc.subject.otherThiosemicarbazoneses_ES
dc.subject.otherX-ray diffractionen_US
dc.subject.otherZinc(II)es_ES
dc.titleSynthesis, characterization and X-ray structures of [α- diphenylethanedione bis(4-ethylthiosemicarbazonato)]palladium(II) and 1,2,4-triazine-3-thione-zinc(II) complexes obtained by metal-induced cyclizationen_US
dc.typearticleen
dc.subject.ecienciaQuímicaes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1002/ejic.200700619es_ES
dc.identifier.doi10.1002/ejic.200700619es_ES
dc.identifier.publicationfirstpage5433es_ES
dc.identifier.publicationlastpage5438es_ES
dc.identifier.publicationvolume34es_ES
dc.type.versioninfo:eu-repo/semantics/acceptedVersionen
dc.rights.accessRightsopenAccessen
dc.facultadUAMFacultad de Ciencias


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