Palladium and organocatalysis: An excellent recipe for asymmetric synthesis

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dc.contributor.author Fernández-Ibañez, M. Ángeles
dc.contributor.author Maciá, Beatriz
dc.contributor.author Alonso, Diego A.
dc.contributor.author Pastor, Isidro M.
dc.contributor.other UAM. Departamento de Química Orgánica es_ES
dc.date.accessioned 2015-07-23T08:02:24Z
dc.date.available 2015-07-23T08:02:24Z
dc.date.issued 2013-09-01
dc.identifier.citation Molecules 18.9 (2013): 10108-10121 en_US
dc.identifier.issn 1420-3049 es_ES
dc.identifier.uri http://hdl.handle.net/10486/667528
dc.description.abstract The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric α-allylation of carbonyl compounds, α-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology en_US
dc.description.sponsorship MAFI thanks financial support from the Ministerio de Economía y Competitividad MINECO, CTQ 2012-35790) and the Consejería de Educación de la Comunidad de Madrid (AVANCAT, S2009/PPQ-1634). BM thanks the European Commission for a Marie Curie Integration Grant (FP7-PEOPLE-2012-CIG). IMP thanks financial support from the Ministerio de Ciencia e Innovación (MICINN) of Spain (CTQ2011-24165) and from the University of Alicante. DAA thanks financial support for the European Union (ORCA action CM0905) and from the University of Alicante en_US
dc.format.extent 14 pag. en
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher MDPI en_US
dc.relation.ispartof Molecules en_US
dc.rights © 2013 by the authors en_US
dc.subject.other Allylation en_US
dc.subject.other Asymmetric synthesis en_US
dc.subject.other Decarboxylative protonation en_US
dc.subject.other Dual activation en_US
dc.subject.other Fluorination en_US
dc.subject.other Organocatalysis en_US
dc.subject.other Palladium en_US
dc.subject.other Tandem reaction en_US
dc.title Palladium and organocatalysis: An excellent recipe for asymmetric synthesis en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.relation.publisherversion http://dx.doi.org/10.3390/molecules180910108 es_ES
dc.identifier.doi 10.3390/molecules180910108 es_ES
dc.identifier.publicationfirstpage 10108 es_ES
dc.identifier.publicationissue 9 es_ES
dc.identifier.publicationlastpage 10121 es_ES
dc.identifier.publicationvolume 18 es_ES
dc.relation.projectID Comunidad de Madrid. S2009/PPQ-1634/AVANCAT es_ES
dc.type.version info:eu-repo/semantics/publishedVersion en
dc.rights.cc Reconocimiento es_ES
dc.rights.accessRights openAccess en


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