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Supramolecular electron transfer-based switching involving pyrrolic macrocycles. A new approach to sensor development?

Author
Bill, Nathan L.; Trukhina, Olga; Sessler, Jonathan L.; Torres Cebada, Tomásuntranslated
Entity
UAM. Departamento de Química Orgánica
Publisher
Royal Society of Chemistry
Date
2015-05-07
Citation
10.1039/c4cc10193f
Chemical Communications 51.37 (2015): 7781-7794
 
 
 
ISSN
1359-7345 (print); 1364-548X (online)
DOI
10.1039/c4cc10193f
Funded by
The work in Austin was supported by the U.S. National Science Foundation (grant CHE-1402004 to J.L.S.) and the Robert A. Welch Foundation (Grant F-1018 to J.L.S.). Financial support from the Spanish MICINN (CTQ2011-24187/BQU) and the Comunidad de Madrid (S2013/MIT-2841 FOTOCARBON) is acknowledged
Project
Gobierno de España. CTQ2011-24187/BQU; Comunidad de Madrid. S2013/MIT-2841/FOTOCARBON
Editor's Version
http://dx.doi.org/10.1039/c4cc10193f
Subjects
Carbon nanotube; Macrocyclic compound; Pyrrole derivative; Química
URI
http://hdl.handle.net/10486/670421
Rights
© The Royal Society of Chemistry 2015

Abstract

This Feature focuses on pyrrolic macrocycles that can serve as switches via energy- or electron transfer (ET) mechanisms. Macrocycles operating by both ground state (thermodynamic) and photoinduced ET pathways are reviewed and their ability to serve as the readout motif for molecular sensors is discussed. The aim of this article is to highlight the potential utility of ET in the design of systems that perform molecular switching or logic functions and their applicability in chemical sensor development. The conceptual benefits of this paradigm are illustrated with examples drawn mostly from the authors' laboratories
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  • Producción científica en acceso abierto de la UAM [17718]

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