Supramolecular electron transfer-based switching involving pyrrolic macrocycles. A new approach to sensor development?
Entity
UAM. Departamento de Química OrgánicaPublisher
Royal Society of ChemistryDate
2015-05-07Citation
10.1039/c4cc10193f
Chemical Communications 51.37 (2015): 7781-7794
ISSN
1359-7345 (print); 1364-548X (online)DOI
10.1039/c4cc10193fFunded by
The work in Austin was supported by the U.S. National Science Foundation (grant CHE-1402004 to J.L.S.) and the Robert A. Welch Foundation (Grant F-1018 to J.L.S.). Financial support from the Spanish MICINN (CTQ2011-24187/BQU) and the Comunidad de Madrid (S2013/MIT-2841 FOTOCARBON) is acknowledgedProject
Gobierno de España. CTQ2011-24187/BQU; Comunidad de Madrid. S2013/MIT-2841/FOTOCARBONEditor's Version
http://dx.doi.org/10.1039/c4cc10193fSubjects
Carbon nanotube; Macrocyclic compound; Pyrrole derivative; QuímicaRights
© The Royal Society of Chemistry 2015Abstract
This Feature focuses on pyrrolic macrocycles that can serve as switches via energy- or electron transfer (ET) mechanisms. Macrocycles operating by both ground state (thermodynamic) and photoinduced ET pathways are reviewed and their ability to serve as the readout motif for molecular sensors is discussed. The aim of this article is to highlight the potential utility of ET in the design of systems that perform molecular switching or logic functions and their applicability in chemical sensor development. The conceptual benefits of this paradigm are illustrated with examples drawn mostly from the authors' laboratories
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Google Scholar:Bill, Nathan L.
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Trukhina, Olga
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Sessler, Jonathan L.
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Torres Cebada, Tomás
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