H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2
Entidad
UAM. Departamento de Química InorgánicaEditor
The Royal Society of ChemistryFecha de edición
2015-08-10Cita
10.1039/c5cc06402c
Chemical Communications 51.81 (2015): 14992-14995
ISSN
1359-7345 (print); 1364-548X (online)DOI
10.1039/c5cc06402cFinanciado por
This work was supported by Spanish Ministerio de Economia y Competitividad (CTQ2012-37420-C02-02 and 01) European Research Council (StG 239910), and Generalitat de Catalunya (2014 SGR 862 and ICREA Academia award to MC). J.Ll.-F. thanks the CELLEX foundation for the starting career program for financial supportProyecto
Gobierno de España. CTQ2012-37420-C02-02; Gobierno de España. CTQ2012-37420-C02-01Versión del editor
http://dx.doi.org/10.1039/c5cc06402cMaterias
Acetic acid; Cyclohexane; Cyclohexanol; Hydrogen; Hydrogen peroxide; Iron complex; QuímicaDerechos
© 2015 The Royal Society of ChemistryResumen
Herein we show that species generated upon reaction of α-[Fe(CF3SO3)2(BPMCN)] (BPMCN = N,N′-bis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane) with H2O2 (putatively [FeV(O)(OH)(BPMCN)]) is able to efficiently oxidize H2 to H2O even in the presence of organic substrates, while species formed in the presence of acetic acid (putatively [FeV(O)(OAc)(BPMCN)]) prefer organic substrate oxidation over H2 activation. Mechanistic implications have been analysed with the aid of computational methods
Lista de ficheros
Google Scholar:Hassanpour, Azin
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Acuña-Parés, Ferran
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Luis, Josep M.
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Cusso, Olaf
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Morales De La Rosa, Silvia
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Campos-Martín, José Miguel
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Costas, Miquel
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Lloret-Fillol, Julio
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Mas Ballesté, Rubén
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Fierro, Jose L. G.
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