H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2

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dc.contributor.author Hassanpour, Azin
dc.contributor.author Acuña-Parés, Ferran
dc.contributor.author Luis, Josep M.
dc.contributor.author Cusso, Olaf
dc.contributor.author Morales De La Rosa, Silvia
dc.contributor.author Campos-Martín, José Miguel
dc.contributor.author Costas, Miquel
dc.contributor.author Lloret-Fillol, Julio
dc.contributor.author Mas-Ballesté, Rubén
dc.contributor.author Fierro, Jose L. G.
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2016-03-31T17:16:07Z
dc.date.available 2016-03-31T17:16:07Z
dc.date.issued 2015-08-10
dc.identifier.citation Chemical Communications 51.81 (2015): 14992-14995 en_US
dc.identifier.issn 1359-7345 (print) es_ES
dc.identifier.issn 1364-548X (online) es_ES
dc.identifier.uri http://hdl.handle.net/10486/670425
dc.description.abstract Herein we show that species generated upon reaction of α-[Fe(CF3SO3)2(BPMCN)] (BPMCN = N,N′-bis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane) with H2O2 (putatively [FeV(O)(OH)(BPMCN)]) is able to efficiently oxidize H2 to H2O even in the presence of organic substrates, while species formed in the presence of acetic acid (putatively [FeV(O)(OAc)(BPMCN)]) prefer organic substrate oxidation over H2 activation. Mechanistic implications have been analysed with the aid of computational methods en_US
dc.description.sponsorship This work was supported by Spanish Ministerio de Economia y Competitividad (CTQ2012-37420-C02-02 and 01) European Research Council (StG 239910), and Generalitat de Catalunya (2014 SGR 862 and ICREA Academia award to MC). J.Ll.-F. thanks the CELLEX foundation for the starting career program for financial support en_US
dc.format.extent 4 pag. es_ES
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher The Royal Society of Chemistry en_US
dc.relation.ispartof Chemical Communications en_US
dc.rights © 2015 The Royal Society of Chemistry en_US
dc.subject.other Acetic acid en_US
dc.subject.other Cyclohexane en_US
dc.subject.other Cyclohexanol en_US
dc.subject.other Hydrogen en_US
dc.subject.other Hydrogen peroxide en_US
dc.subject.other Iron complex en_US
dc.title H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2 en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c5cc06402c es_ES
dc.identifier.doi 10.1039/c5cc06402c es_ES
dc.identifier.publicationfirstpage 14992 es_ES
dc.identifier.publicationissue 81 es_ES
dc.identifier.publicationlastpage 14995 es_ES
dc.identifier.publicationvolume 51 es_ES
dc.relation.projectID Gobierno de España. CTQ2012-37420-C02-02 es_ES
dc.relation.projectID Gobierno de España. CTQ2012-37420-C02-01 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion en
dc.rights.accessRights openAccess en

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