Universidad Autónoma de Madrid

On-surface self-organization of a robust metal-organic cluster based on copper(i) with chloride and organosulphur ligands

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On-surface self-organization of a robust metal-organic cluster based on copper(i) with chloride and organosulphur ligands

Metadatos
Title: On-surface self-organization of a robust metal-organic cluster based on copper(i) with chloride and organosulphur ligands
Author: Otero-Irurueta, Gonzalo; Hernández-Rodríguez, Irene; Martínez, José Ignacio; Palacios-Rivera, Rogger; Palomares, Francisco J.; López, María F.; Gallego, Almudena I.; Delgado, Salomé; Zamora, Félix; Méndez, Javier; Martín-Gago, José A.
Entity: UAM. Departamento de Química Inorgánica
Publisher: The Royal Society of Chemistry
Date: 2015-02-21
Citation: Chemical Communications 51.15 (2015): 3243-3246
ISSN: 1359-7345 (print); 1364-548X (online)
DOI: 10.1039/C4CC08471C
Funded by: We thank Spanish MINECO (Grants: MAT2013-46753-C2-1-P, MAT2013-47878-C2-1-R and MAT2011-26534) for financial support. JIM acknowledges a CSIC-JaeDoc fellowship, cofunded by ESF
Project: Gobierno de España. MAT2013-46753-C2-1-P; Gobierno de España. MAT2013-47878-C2-1-R; Gobierno de España. MAT2011-26534
Editor's Version: http://dx.doi.org/10.1039/C4CC08471C
Subjects: Chloride; Copper; Metal organic framework; Organosulfur derivative; Química
URI: http://hdl.handle.net/10486/670585
Rights: © The Royal Society of Chemistry 2015

Abstract:

Direct sublimation of a Cu4Cl4 metal-organic cluster on Cu(110) under ultra-high vacuum allows the formation of ultra-large well-organized metal-organic supramolecular wires. Our results show that the large monomers assemble with each other by π-π interactions connecting dipyrimidine units and are stabilized by the surface

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Citations
G o o g l e ™ Scholar: Otero-Irurueta, Gonzalo - Hernández-Rodríguez, Irene - Martínez, José Ignacio - Palacios-Rivera, Rogger - Palomares, Francisco J. - López, María F. - Gallego, Almudena I. - Delgado, Salomé - Zamora, Félix - Méndez, Javier - Martín-Gago, José A.

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