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On-surface self-organization of a robust metal-organic cluster based on copper(i) with chloride and organosulphur ligands

Author
Otero-Irurueta, Gonzalo; Hernández-Rodríguez, Irene; Martínez, José Ignacio; Palacios-Rivera, Rogger; Palomares, Francisco J.; López, María F.; Gallego, Almudena I.; Delgado, Salomé; Zamora, Félix; Méndez, Javier; Martín-Gago, José A.
Entity
UAM. Departamento de Química Inorgánica
Publisher
The Royal Society of Chemistry
Date
2015-02-21
Citation
Chemical Communications 51.15 (2015): 3243-3246
ISSN
1359-7345 (print); 1364-548X (online)
DOI
10.1039/C4CC08471C
Funded by
We thank Spanish MINECO (Grants: MAT2013-46753-C2-1-P, MAT2013-47878-C2-1-R and MAT2011-26534) for financial support. JIM acknowledges a CSIC-JaeDoc fellowship, cofunded by ESF
Project
Gobierno de España. MAT2013-46753-C2-1-P; Gobierno de España. MAT2013-47878-C2-1-R; Gobierno de España. MAT2011-26534
Editor's Version
http://dx.doi.org/10.1039/C4CC08471C
Subjects
Chloride; Copper; Metal organic framework; Organosulfur derivative; Química
URI
http://hdl.handle.net/10486/670585
Rights
© The Royal Society of Chemistry 2015

Abstract

Direct sublimation of a Cu4Cl4 metal-organic cluster on Cu(110) under ultra-high vacuum allows the formation of ultra-large well-organized metal-organic supramolecular wires. Our results show that the large monomers assemble with each other by π-π interactions connecting dipyrimidine units and are stabilized by the surface
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Google™ Scholar:Otero-Irurueta, Gonzalo - Hernández-Rodríguez, Irene - Martínez, José Ignacio - Palacios-Rivera, Rogger - Palomares, Francisco J. - López, María F. - Gallego, Almudena I. - Delgado, Salomé - Zamora, Félix - Méndez, Javier - Martín-Gago, José A.

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