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Stereochemical aspects and the synthetic scope of the SHi at the sulfur atom. Preparation of enantiopure 3-substituted 2,3-dihydro-1,2- benzoisothiazole 1-oxides and 1,1-dioxides

dc.contributor.authorFernández Salas, José Antonio 
dc.contributor.authorRodríguez-Fernández, M. Mercedes
dc.contributor.authorMaestro Rubio, Carmen 
dc.contributor.authorGarcía-Ruano, José L.
dc.contributor.otherUAM. Departamento de Química Orgánicaes_ES
dc.date.accessioned2016-05-13T17:12:26Z
dc.date.available2016-05-13T17:12:26Z
dc.date.issued2014-06-07
dc.identifier.citationChemical Communications 50.45 (2014): 6046-6048en_US
dc.identifier.issn1359-7345 (print)es_ES
dc.identifier.issn1364-548X (online)es_ES
dc.identifier.urihttp://hdl.handle.net/10486/670860
dc.description.abstractIntramolecular homolytic substitution (SHi) on the sulfur atom at acyclic N-(o-bromobenzyl)sulfinamides takes place with a complete inversion of the configuration and provides an excellent tool to connect N-tert-butanesulfinylimines with enantiopure 3-substituted benzo-fused sulfinamides (1,2-benzoisothiazoline 1-oxides) and the related pharmacologically relevant sulfonamidesen_US
dc.description.sponsorshipThe Spanish Government (grant CTQ2012-35957) and Comunidad de Madrid (CCG08-UAM/PPQ-4151; S2009/PPQ1634)en_US
dc.format.extent3 pag.es_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherThe Royal Society of Chemistryen_US
dc.relation.ispartofChemical Communicationsen_US
dc.rights© the Partner Organisations 2014en_US
dc.rights© The Royal Society of Chemistry 2014en_US
dc.subject.otherSulfinamideen_US
dc.subject.otherSulfonamideen_US
dc.subject.otherSulfoxideen_US
dc.subject.otherSulfuren_US
dc.titleStereochemical aspects and the synthetic scope of the SHi at the sulfur atom. Preparation of enantiopure 3-substituted 2,3-dihydro-1,2- benzoisothiazole 1-oxides and 1,1-dioxidesen_US
dc.typearticleen
dc.subject.ecienciaQuímicaes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c4cc01831aes_ES
dc.identifier.doi10.1039/c4cc01831aes_ES
dc.identifier.publicationfirstpage6046es_ES
dc.identifier.publicationissue45es_ES
dc.identifier.publicationlastpage6048es_ES
dc.identifier.publicationvolume50es_ES
dc.relation.projectIDGobierno de España. CTQ2012-35957es_ES
dc.relation.projectIDComunidad de Madrid. S2009/PPQ1634/AVANCATes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.rights.accessRightsopenAccessen
dc.authorUAMFernández Salas, José Antonio (264081)
dc.facultadUAMFacultad de Ciencias


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