Mechanical and optical properties of ultralarge flakes of a metal-organic framework with molecular thickness

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dc.contributor.author Hermosa, Cristina
dc.contributor.author Horrocks, Benjamin R.
dc.contributor.author Martínez, José Ignacio
dc.contributor.author Liscio, Fabiola
dc.contributor.author Gómez-Herrero, Julio
dc.contributor.author Zamora, Félix
dc.contributor.other UAM. Departamento de Física de la Materia Condensada es_ES
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2016-05-20T14:22:06Z
dc.date.available 2016-05-20T14:22:06Z
dc.date.issued 2015-04-01
dc.identifier.citation Chemical Science 6.4 (2015): 2553-2558 en_US
dc.identifier.issn 2041-6520 (print) es_ES
dc.identifier.issn 2041-6539 (online) es_ES
dc.identifier.uri http://hdl.handle.net/10486/670991
dc.description.abstract The isolation of 2D-materials is already a success for graphene, graphene oxide, boron nitride and a few clays or metal chalcogenides, however despite the fact that some of them show very interesting physical properties, they lack useful functionalities. Metal-Organic Frameworks (MOFs) are multifunctional materials showing a wide range of physical and chemical properties that can be structurally designed by suitable selection of their building-blocks. This strategy may allow the production of layers with a variety of useful electronic and molecular recognition functionalities. Herein we isolate 2D-MOF flakes with areas of hundreds of square microns and an excellent control of the molecular thickness (from single up to ca. 50 layers). The samples exhibit such good photoluminescence and mechanical properties as to allow free-standing characterization of few layers' flakes en_US
dc.description.sponsorship The authors acknowledge financial support from MICINN (MAT2013-46753-C2-1-P and MAT2013-46753-C2-2-P and Consolider CSD2010-00024) en_US
dc.format.extent 6 pag. es_ES
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher The Royal Society of Chemistry en_US
dc.relation.ispartof Chemical Science en_US
dc.rights © The Royal Society of Chemistry en_US
dc.subject.other Characterization en_US
dc.subject.other Crystalline materials en_US
dc.subject.other Graphene en_US
dc.subject.other Inorganic compounds en_US
dc.subject.other Mechanical properties en_US
dc.subject.other Organic polymers en_US
dc.subject.other Organometallics en_US
dc.subject.other Metal chalcogenide en_US
dc.subject.other Molecular thickness en_US
dc.title Mechanical and optical properties of ultralarge flakes of a metal-organic framework with molecular thickness en_US
dc.type article en
dc.subject.eciencia Física es_ES
dc.subject.eciencia Química es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c4sc03115f es_ES
dc.identifier.doi 10.1039/c4sc03115f es_ES
dc.identifier.publicationfirstpage 2553 es_ES
dc.identifier.publicationissue 4 es_ES
dc.identifier.publicationlastpage 2558 es_ES
dc.identifier.publicationvolume 6 es_ES
dc.relation.projectID Gobierno de España. MAT2013-46753-C2-1-P es_ES
dc.relation.projectID Gobierno de España. MAT2013-46753-C2-2-P es_ES
dc.relation.projectID Gobierno de España. CSD2010-00024 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion en
dc.rights.cc Reconocimiento es_ES
dc.rights.accessRights openAccess en
dc.authorUAM Hermosa Del Olmo, Cristina (264203)


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