Charge transfer-assisted self-limited decyanation reaction of TCNQ-type electron acceptors on Cu(100)
Entity
UAM. Departamento de Física Teórica de la Materia Condensada; UAM. Departamento de QuímicaPublisher
The Royal Society of ChemistryDate
2014-01-25Citation
10.1039/c3cc45791e
Chemical Communications 50.7 (2014): 833-835
ISSN
1359-7345 (print); 1364-548X (online)DOI
10.1039/c3cc45791eFunded by
We thank the CCC-UAM and the RES for allocation of computer time. Our work has been supported by the MINECO of Spain (MAT2009-13488, FIS2010-18847, FIS2010-15127, FIS2012-33011, CTQ2010-17006, CTQ2011-24652/BTQ), Comunidad de Madrid (Nanobiomagnet S2009/MAT-1726, Madrisolar-2 S2009/PPQ-1533), CONSOLIDER-INGENIO on Molecular Nanoscience (CSD2007- 00010) and European Union (SMALL PITN-GA-2009-23884)Project
Gobierno de España. MAT2009-13488; Gobierno de España. FIS2010-18847; Gobierno de España. FIS2010-15127; Gobierno de España. FIS2012-33011; Gobierno de España. CTQ2010-17006; Gobierno de España. CTQ2011-24652/BTQ; Comunidad de Madrid. S2009/MAT-1726/Nanobiomagnet; Comunidad de Madrid. S2009/PPQ-1533/Madrisolar-2; Gobierno de España. CSD2007-00010Editor's Version
http://dx.doi.org/10.1039/c3cc45791eSubjects
15,15,16,16 tetracyano 6,13 pentacene 4 quinodimethane; Copper; Methane; Unclassified drug; Física; QuímicaRights
© The Royal Society of Chemistry 2014Abstract
TCNQ derivatives adsorbed on a metal surface undergo a self-limited decyanation reaction that only affects two out of the four cyano groups in the molecule. Combined Scanning Tunneling Microscopy/X-ray Photoelectron Spectroscopy experiments and Density Functional Theory calculations relate the self-limiting behavior to the transfer of electrons from the metal to the molecule
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Google Scholar:Urban, Christian
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Wang, Yang
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Rodríguez-Fernández, Jonathan
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García, Raúl
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Herranz, M. Ángeles
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Alcamí Pertejo, Manuel
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Martín, Nazario
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Martín García, Fernando
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Gallego, José M.
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Miranda Soriano, Rodolfo
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Otero Martín, Roberto
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