Quantum control of isomerization by robust navigation in the energy spectrum
Entity
UAM. Departamento de QuímicaPublisher
American Institute of Physics Publising LLCDate
2015-12-07Citation
10.1063/1.4936424
Journal of Chemical Physics 143.21 (2015): 214305
ISSN
0021-9606 (print); 1089-7690 (online)DOI
10.1063/1.4936424Funded by
This research was supported by the Ministry of Economy and Competitiveness-Spain under Contract Nos. MTM2012- 39101 and ICMAT Severo Ochoa SEV-2001-0087, ANPCyTArgentina (PICT-1187), and CONICET-Argentina (PIP- 00273)Project
Gobierno de España. MTM2012- 39101; Gobierno de España. SEV-2001-0087Editor's Version
http://dx.doi.org/10.1063/1.4936424Subjects
Control theory; Electric fields; Hamiltonians; Isomerization; QuímicaRights
© 2015 AIP Publishing LLCAbstract
In this paper, we present a detailed study on the application of the quantum control technique of navigation in the energy spectrum to chemical isomerization processes, namely, CN-Li → ←Li-CN. This technique is based on the controlled time variation of a Hamiltonian parameter, an external uniform electric field in our case. The main result of our work establishes that the navigation involved in the method is robust, in the sense that quite sizable deviations from a pre-established control parameter time profile can be introduced and still get good final results. This is specially relevant thinking of a experimental implementation of the method
Files in this item
Google Scholar:Murgida, G.E.
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Arranz, F. J.
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Borondo, Florentino
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