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Self-assembly of 1D/2D hybrid nanostructures consisting of a Cd(II) coordination polymer and NiAl-layered double hydroxides

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Self-assembly of 1D/2D hybrid nanostructures consisting of a Cd(II) coordination polymer and NiAl-layered double hydroxides

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Title: Self-assembly of 1D/2D hybrid nanostructures consisting of a Cd(II) coordination polymer and NiAl-layered double hydroxides
Author: Abellán, Gonzalo; Amo-Ochoa, P.; Fierro, J.G.; Ribera, Antonio; Coronado, E.; Zamora, F.
Entity: UAM. Departamento de Química Inorgánica
Publisher: MDPI AG
Date: 2015-12-29
Citation: Polymers 8.1 (2016): 5
ISSN: 2073-4360
DOI: 10.3390/polym8010005
Funded by: Financial support from the EU (FET-OPEN 2D-INK. Grant agreement 648786), the Spanish MINECO (Projects MAT2011-22785, MAT2013-46753-C2-1-P, MAT2013-46502-C2-2-P and CTQ-2011-26507), and the Generalitat Valenciana (Prometeo Program and ISIC-Nano) is gratefully acknowledged. Gonzalo Abellán thanks the EU for a Marie Curie Fellowship (FP7/2013-IEF-627386).
Project: info:eu-repo/grantAgreement/EC/H2020/664878/EU//2D-INK; Gobierno de España. MAT2011-22785; Gobierno de España. MAT2013-46753-C2-1-P; Gobierno de España. MAT2013-46502-C2-2-P; Gobierno de España. CTQ-2011-26507; info:eu-repo/grantAgreement/EC/FP7/627386
Editor's Version: http://dx.doi.org/10.3390/polym8010005
Subjects: Coordination polymers; Hybrid materials; Layered compounds; Layered double hydroxides; Magnetic properties; Química
URI: http://hdl.handle.net/10486/678544
Rights: © 2015 by the authors

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Abstract:

The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora of different functional hybrid systems

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G o o g l e ™ Scholar: Abellán, Gonzalo - Amo-Ochoa, P. - Fierro, J.G. - Ribera, Antonio - Coronado, E. - Zamora, F.

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