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Mañana, JUEVES, 24 DE ABRIL, el sistema se apagará debido a tareas habituales de mantenimiento a partir de las 9 de la mañana. Lamentamos las molestias.

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Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst

dc.contributor.authorJarava-Barrera, Carlos
dc.contributor.authorParra, Alejandro
dc.contributor.authorAmenós, Laura
dc.contributor.authorArroyo, Ana
dc.contributor.authorTortosa Manzanares, Mariola 
dc.contributor.otherUAM. Departamento de Química Orgánicaes_ES
dc.date.accessioned2018-01-17T08:45:51Z
dc.date.available2018-01-17T08:45:51Z
dc.date.issued2017-12-11
dc.identifier.citationChemistry: A European Journal 23.69 (2017): 17478 –17481en_US
dc.identifier.issn0947-6539 (print)en_US
dc.identifier.issn1521-3765 (online)en_US
dc.identifier.urihttp://hdl.handle.net/10486/680854
dc.descriptionThis is the peer reviewed version of the following article: Chemistry: A European Journal 23.69 (2017): 17478 –17481, which has been published in final form at http://doi.org/10.1002/chem.201705019. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archivingen_US
dc.description.abstractChiral α-allenols are prepared with high diastereocontrol through an unprecedented and spontaneous β-oxygen elimination of an α-epoxy vinyl boronate. Stochiometric experiments and DFT calculations support a dual role of the copper catalyst, which orchestrates the hydroboration and the syn-elimination stepen_US
dc.description.sponsorshipThe European ResearchCouncil (ERC-337776) and MINECO (CTQ2016-78779-R) for financial support M.T.thanks MICINNfor a RyC contracten_US
dc.format.extent6 pag.es_ES
dc.format.mimetypeapplication/pdfen_US
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.ispartofChemistry - A European Journalen_US
dc.rights© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.subject.otherallenesen_US
dc.subject.otherboronen_US
dc.subject.othercopperen_US
dc.subject.otherepoxidesen_US
dc.subject.otherstereoselective synthesisen_US
dc.titleStereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalysten_US
dc.typearticleen_US
dc.subject.ecienciaQuímicaes_ES
dc.date.embargoend2018-11-24
dc.relation.publisherversionhttp://doi.org/10.1002/chem.201705019es_ES
dc.identifier.doi10.1002/chem.201705019es_ES
dc.identifier.publicationfirstpage17478es_ES
dc.identifier.publicationissue69es_ES
dc.identifier.publicationlastpage17481es_ES
dc.identifier.publicationvolume23es_ES
dc.relation.projectIDGobierno de España. CTQ2016-78779-Res_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/337776es_ES
dc.type.versioninfo:eu-repo/semantics/acceptedVersionen_US
dc.rights.accessRightsopenAccessen_US
dc.authorUAMParra Sánchez, Alejandro (263577)
dc.authorUAMTortosa Manzanares, Mariola (264632)
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMInstituto de Investigación Avanzada en Ciencias Químicas (IAdChem)


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