Polaritonic Chemistry with organic molecules
EntidadUAM. Departamento de Física Teórica de la Materia Condensada
EditorAmerican Chemical Society
Fecha de edición2018-01-17
10.1021/acsphotonics.7b00680ACS Photonics 5.1 (2018): 205 - 216
Financiado porThis work has been funded by the European Research Council under grant agreements ERC-2011-AdG-290981 and ERC-2016-STG- 714870, by the European Union Seventh Frame-work Programme under grant agreement FP7-PEOPLE-2013-CIG-618229, and the Spanish MINECO under contractMAT2014-53432-C5-5-R and the“María de Maeztu”programfor Units of Excellence in R&D (MDM-2014-0377).
Proyectoinfo:eu-repo/grantAgreement/EC/FP7/290981; info:eu-repo/grantAgreement/EC/H2020/714870; info:eu-repo/grantAgreement/EC/FP7/618229; Gobierno de España. MAT2014-53432-C5-5-R; Gobierno de España. MDM-2014-0377
Versión del editorhttp://doi.org/10.1021/acsphotonics.7b00680
Materiasorganic molecules; photochemistry; polaritonic chemistry; quantum optics; Física
NotaThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Photonics, copyright © 2017 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acsphotonics.7b00680
Derechos© 2017 American Chemical Society
We present an overview of the general concepts of polaritonic chemistry with organic molecules, i.e., the manipulation of chemical structure that can be achieved through strong coupling between confined light modes and organic molecules. Strong coupling and the associated formation of polaritons, hybrid light-matter excitations, lead to energy shifts in such systems that can amount to a large fraction of the uncoupled transition energy. This has recently been shown to significantly alter the chemical structure of the coupled molecules, which opens the possibility to manipulate and control reactions. We discuss the current state of theory for describing these changes and present several applications, with a particular focus on the collective effects observed when many molecules are involved in strong coupling
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