Asymmetric induction in photocatalysis – Discovering a new side to light-driven chemistry
Entity
UAM. Departamento de Química OrgánicaDate
2018-02-16Citation
10.1016/j.tetlet.2018.02.040
Tetrahedron Letters 59.14 (2018):1286-1294
ISSN
0040-4039DOI
10.1016/j.tetlet.2018.02.040Funded by
Spanish Government (CTQ2015-64561-R) and the European Research Council (ERC-CG, contract number: 647550) areacknowledgedProject
Gobierno de España. CTQ2015-64561-R; info:eu-repo/grantAgreement/EC/FP7/647550Subjects
Asymmetric catalysis; Lewis acid catalysis; Organocatalysis; Photocatalysis; Photochemistry; QuímicaNote
Embargo de 24 meses desde fecha de publicación por política editorialRights
© 2018 Elsevier LtdEsta obra está bajo una licencia de Creative Commons Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional.
Abstract
The state of asymmetric photocatalysis is exceptionally promising, as chemists from different fields and backgrounds have converged to solve a longstanding issue: stereocontrol in photochemistry. As a strategy that relies heavily on the elevated reactivity of radical intermediates, managing to suppress the background racemic reactions in favor of the stereoselective processes is a challenging endeavor many researchers have embarked on. In order to tackle this matter, conceptually diverse activation modes have been developed, obtaining valuable results across mechanistically-distinct types of reactions, all while setting the stage for future breakthroughs in the field
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Google Scholar:Garrido-Castro, Alberto F.
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Maestro Rubio, Carmen
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Alemán Lara, José Julián
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