Plasmonic Nanocavities Enable Self-Induced Electrostatic Catalysis
Entity
UAM. Departamento de Física Teórica de la Materia CondensadaPublisher
Wiley-VCH VerlagDate
2019-06-13Citation
10.1002/anie.201901926
Angewandte Chemie - International Edition 58.26 (2019): 8698-8702
ISSN
1433-7851 (print); 1521-3773 (online)DOI
10.1002/anie.201901926Funded by
This work has been funded by the European Research Council (ERC‐2016‐STG‐714870) and the Spanish MINECO under contract MAT2014‐53432‐C5‐5‐R and the “María de Maeztu” programme for Units of Excellence in R&D (MDM‐2014‐0377), as well as through a Ramón y Cajal grant (JF). We also acknowledge support by the QuantERA program of the European Commission with funding by the Spanish AEI through project PCI2018‐093145Project
info:eu-repo/grantAgreement/EC/H2020/714870/EU//MMUSCLES; Gobierno de España. MAT2014‐53432‐C5‐5‐R; Gobierno de España. MDM‐2014‐0377; info:eu-repo/grantAgreement/EC/H2020/731473/EU//QuantERA; Gobierno de España. PCI2018‐093145Editor's Version
https://doi.org/10.1002/anie.201901926Subjects
Spin crossover; Self-induced catalysis; Plasmonic nanocavity; Nucleophilic substitution; Heterogeneous catalysis; FísicaRights
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Esta obra está bajo una licencia de Creative Commons Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional.
Abstract
The potential of strong interactions between light and matter remains to be further explored within a chemical context. Towards this end herein we study the electromagnetic interaction between molecules and plasmonic nanocavities. By means of electronic structure calculations, we show that self-induced catalysis emerges without any external stimuli through the interaction of the molecular permanent and fluctuating dipole moments with the plasmonic cavity modes. We also exploit this scheme to modify the transition temperature T1/2 of spin-crossover complexes as an example of how strong light–matter interactions can ultimately be used to control a materials responses
Files in this item
Google Scholar:Climent, Clàudia
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Galego, Javier
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García Vidal, Fco. José
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Feist, Johannes
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