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Plasmonic Nanocavities Enable Self-Induced Electrostatic Catalysis
dc.contributor.author | Climent, Clàudia | |
dc.contributor.author | Galego, Javier | |
dc.contributor.author | García Vidal, Fco. José | |
dc.contributor.author | Feist, Johannes | |
dc.contributor.other | UAM. Departamento de Física Teórica de la Materia Condensada | es_ES |
dc.date.accessioned | 2019-08-21T10:18:39Z | |
dc.date.available | 2019-08-21T10:18:39Z | |
dc.date.issued | 2019-06-13 | |
dc.identifier.citation | Angewandte Chemie - International Edition 58.26 (2019): 8698-8702 | en_US |
dc.identifier.issn | 1433-7851 (print) | en_US |
dc.identifier.issn | 1521-3773 (online) | en_US |
dc.identifier.uri | http://hdl.handle.net/10486/688400 | |
dc.description.abstract | The potential of strong interactions between light and matter remains to be further explored within a chemical context. Towards this end herein we study the electromagnetic interaction between molecules and plasmonic nanocavities. By means of electronic structure calculations, we show that self-induced catalysis emerges without any external stimuli through the interaction of the molecular permanent and fluctuating dipole moments with the plasmonic cavity modes. We also exploit this scheme to modify the transition temperature T1/2 of spin-crossover complexes as an example of how strong light–matter interactions can ultimately be used to control a materials responses | en_US |
dc.description.sponsorship | This work has been funded by the European Research Council (ERC‐2016‐STG‐714870) and the Spanish MINECO under contract MAT2014‐53432‐C5‐5‐R and the “María de Maeztu” programme for Units of Excellence in R&D (MDM‐2014‐0377), as well as through a Ramón y Cajal grant (JF). We also acknowledge support by the QuantERA program of the European Commission with funding by the Spanish AEI through project PCI2018‐093145 | en_US |
dc.format.extent | 6 pag. | en_US |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Wiley-VCH Verlag | en_US |
dc.relation.ispartof | Angewandte Chemie - International Edition | en_US |
dc.rights | © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | en_US |
dc.subject.other | Spin crossover | en_US |
dc.subject.other | Self-induced catalysis | en_US |
dc.subject.other | Plasmonic nanocavity | en_US |
dc.subject.other | Nucleophilic substitution | en_US |
dc.subject.other | Heterogeneous catalysis | en_US |
dc.title | Plasmonic Nanocavities Enable Self-Induced Electrostatic Catalysis | en_US |
dc.type | article | en |
dc.subject.eciencia | Física | es_ES |
dc.date.embargoend | 2020-06-13 | |
dc.relation.publisherversion | https://doi.org/10.1002/anie.201901926 | es_ES |
dc.identifier.doi | 10.1002/anie.201901926 | es_ES |
dc.identifier.publicationfirstpage | 8698 | es_ES |
dc.identifier.publicationissue | 26 | es_ES |
dc.identifier.publicationlastpage | 8702 | es_ES |
dc.identifier.publicationvolume | 58 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/714870/EU//MMUSCLES | en_US |
dc.relation.projectID | Gobierno de España. MAT2014‐53432‐C5‐5‐R | es_ES |
dc.relation.projectID | Gobierno de España. MDM‐2014‐0377 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/731473/EU//QuantERA | en_US |
dc.relation.projectID | Gobierno de España. PCI2018‐093145 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.rights.cc | Reconocimiento – NoComercial – SinObraDerivada | es_ES |
dc.rights.accessRights | openAccess | en |
dc.authorUAM | Climent I Biescas, Claudia (279566) | |
dc.authorUAM | García Vidal, Fco. José (259819) | |
dc.authorUAM | Feist, Johannes Maximilian (264839) | |
dc.facultadUAM | Facultad de Ciencias | |
dc.institutoUAM | Centro de Investigación en Física de la Materia Condensada (IFIMAC) |