Multifunctional Copper(I) Coordination Polymers with Aromatic Mono- and Ditopic Thioamides

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Show simple item record Troyano, Javier Zapata, Eduardo Perles, Josefina Amo-Ochoa, Pilar Fernández-Moreira, Vanesa Martínez, José I. Zamora, Félix Delgado, Salomé
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES 2019-09-27T12:16:52Z 2019-09-27T12:16:52Z 2019-03-04
dc.identifier.citation Inorganic Chemistry 58.5 (2019): 3290-3301 en_US
dc.identifier.issn 1520-510X (online) en_US
dc.identifier.issn 0020-1669 (print) en_US
dc.description This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry 58.5 (2019): 3290-3301, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see: en_US
dc.description.abstract Direct reactions under ambient conditions between CuX (X = Br, I) and thiobenzamide (TBA) were carried out at different ratios, giving rise to the formation of a series of one-dimensional (1D) coordination polymers, (CPs) [CuI(TBA)] n (1), [Cu 3 I 3 (TBA) 2 ] n (4), and [CuBr(TBA)] n (5), as well as two molecular complexes, [CuI(TBA) 3 ] (2) and [Cu 2 I 2 (TBA) 4 ]·2MeCN (3). Recrystallization of 1 and 5 yielded a series of isostructural 1D CP solvated species, [CuI(TBA)·S] n ] n (1·S; S = tetrahydrofuran, acetone, methanol) and [CuBr(TBA)·S] n (5·S; S = tetrahydrofuran, acetone), respectively. Similar reactions between CuI and 1,4-dithiobenzamide (DTBA) allowed the isolation of a series of two-dimensional (2D) CPs [CuI(DTBA)·S] n (6·S; S = N,N-dimethylformamide, acetonitrile, methanol). Interestingly, 1·S and 5·S showed variable luminescence and electrical semiconductivity depending on the different solvents located in their structures. Thus, 1 and 5 could display potential application for sensing volatile organic vapors by virtue of the significant changes in their emission upon solvent exposure, even by the naked eye. Theoretical calculations have been used to rationalize these electronic properties en_US
dc.description.sponsorship MINECO (Grants MAT2016-77608-C3-1-P, MAT2016-75883-C2-1-P, and MAT2017-5089-C2-1-R; Ramon y Cajal, Grant RYC-2015-17730), Ministerio de Ciencia, Innovacion y Universidades (Grant CTQ2016-75816-C2-1-P), and European Union’s Horizon 2020 research and innovation programme (Grant 785219; Graphene Flagship−core2) en_US
dc.format.extent 43 pag. en_US
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher American Chemical Society en_US
dc.relation.ispartof Inorganic Chemistry en_US
dc.rights © 2019 American Chemical Society en_US
dc.subject.other Coordination Polymers en_US
dc.subject.other Luminescence en_US
dc.subject.other Fluorescence en_US
dc.subject.other Thioamides en_US
dc.title Multifunctional Copper(I) Coordination Polymers with Aromatic Mono- and Ditopic Thioamides en_US
dc.type article en
dc.subject.eciencia Química es_ES 2020-03-04
dc.relation.publisherversion es_ES
dc.identifier.doi 10.1021/acs.inorgchem.8b03364 es_ES
dc.identifier.publicationfirstpage 3290 es_ES
dc.identifier.publicationissue 5 es_ES
dc.identifier.publicationlastpage 3301 es_ES
dc.identifier.publicationvolume 58 es_ES
dc.relation.projectID Gobierno de España. MAT2016-77608-C3-1-P es_ES
dc.relation.projectID Gobierno de España. MAT2016-75883-C2-1-P es_ES
dc.relation.projectID Gobierno de España. MAT2017-5089-C2-1-R es_ES
dc.relation.projectID Gobierno de España. RYC-2015-17730 es_ES
dc.relation.projectID Gobierno de España. CTQ2016-75816-C2-1-P es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/785219/EU//GrapheneCore2 en_US
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.accessRights openAccess en
dc.authorUAM Perles Hernáez, Josefina (281166)
dc.authorUAM Amo Ochoa, María Pilar (261554)
dc.authorUAM Zamora Abanades, Félix Juan (258846)
dc.authorUAM Delgado Gil, Salomé (259692)

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