UAM_Biblioteca | Unified search engine | Scientific Production Portal | UAM Research Data Repository
Universidad Autónoma de Madrid
Biblos-e Archivo
We are onFacebookCanal BiblosYouTubeTwitterPinterestWhatsappInstagram
    • español
    • English
  • English 
    • español
    • English
  • Log in
JavaScript is disabled for your browser. Some features of this site may not work without it.

Search Biblos-e Archivo

Advanced Search

Browse

All of Biblos-e ArchivoCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsFacultiesThis CollectionBy Issue DateAuthorsTitlesSubjectsFaculties

My Account

Log inRegister

Statistics

View Usage Statistics

Help

Information about Biblos-e ArchivoI want to submit my workI want to submit my doctoral thesisFrequently Asked QuestionsCopyrightsFinancial Agencies and OA policy

UAM_Biblioteca

View Item 
  •   Biblos-e Archivo
  • 1 - Producción científica en acceso abierto de la UAM
  • Producción científica en acceso abierto de la UAM
  • View Item
  •   Biblos-e Archivo
  • 1 - Producción científica en acceso abierto de la UAM
  • Producción científica en acceso abierto de la UAM
  • View Item

A MOF@COF Composite with Enhanced Uptake through Interfacial Pore Generation

Author
Garzón-Tovar, Luis; Pérez-Carvajal, Javier; Yazdi, Amirali; Hernández-Muñoz, Jose; Tarazona, Pedro; Imaz, Inhar; Zamora, Félix; Maspoch, Daniel
Entity
UAM. Departamento de Física Teórica de la Materia Condensada; UAM. Departamento de Química Inorgánica
Publisher
Wiley-VCH Verlag
Date
2019-07-08
Citation
10.1002/anie.201904766
Angewandte Chemie - International Edition 58.28 (2019): 9512-9516
 
 
 
ISSN
1521-3773 (online); 1433-7851 (print)
DOI
10.1002/anie.201904766
Funded by
This work was supported by the Spanish MINECO (projects PN MAT2016-77608-C3-1-P, FIS2017-86007-C3 and FPU2015/0248), the Catalan AGAUR (project 2014 SGR 80), the ERC, under EU-FP7 (ERC-Co 615954), and the CERCA Program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV-2017-0706). IFIMAC is supported by the Maria de Maeztu program (Grant No. MDM-2014-0377)
Project
Gobierno de España. MAT2016-77608-C3-1-P; Gobierno de España. FIS2017-86007-C3; Gobierno de España. FPU2015/0248; Gobierno de España. SEV-2017-0706; Gobierno de España. MDM-2014-0377; info:eu-repo/grantAgreement/EC/FP7/615954
Editor's Version
https://doi.org/10.1002/ange.201904766
Subjects
Metal-organic frameworks; Interfaces; Hierarchical porosity; Covalent-organic frameworks; Composite materials; Química
URI
http://hdl.handle.net/10486/688694
Note
This is the peer reviewed version of the following article: Angewandte Chemie - International Edition 58.28 (2019): 9512-9516, which has been published in final form at https://doi.org/10.1002/ange.201904766. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions
Título del postprint: Enhanced Uptake in a MOF@COF Composite by Interfacial Pore Generation
Rights
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Abstract

Herein, we describe a new class of porous composites comprising metal–organic framework (MOF) crystals confined in single spherical matrices made of packed covalent-organic framework (COF) nanocrystals. These MOF@COF composites are synthesized through a two-step method of spray-drying and subsequent amorphous (imine-based polymer)-to-crystalline (imine-based COF) transformation. This transformation around the MOF crystals generates micro- and mesopores at the MOF/COF interface that provide far superior porosity compared to that of the constituent MOF and COF components added together. We report that water sorption in these new pores occurs within the same pressure window as in the COF pores. Our new MOF@COF composites, with their additional pores at the MOF/COF interface, should have implications for the development of new composites
Show full item record

Files in this item

Thumbnail
Name
MOFCOF_zamora_achie_2019_ps.pdf
Size
1.006Mb
Format
PDF
Thumbnail
Name
SI_MOFCOF_zamora_achie_2019.pdf
Size
3.683Mb
Format
PDF
Description
Article supporting information

Refworks Export

Delicious Save this on Delicious

Google™ Scholar:Garzón-Tovar, Luis - Pérez-Carvajal, Javier - Yazdi, Amirali - Hernández-Muñoz, Jose - Tarazona, Pedro - Imaz, Inhar - Zamora, Félix - Maspoch, Daniel

This item appears in the following Collection(s)

  • Producción científica en acceso abierto de la UAM [15090]

Related items

Showing items related by title, author, creator and subject.

  • Spray drying for making covalent chemistry II: Synthesis of covalent-organic framework superstructures and related composites 

    Garzón-Tovar, Luis; Avci-Camur, Ceren; Rodríguez-San-Miguel, David; Imaz, Inhar; Zamora, Félix; Maspoch, Daniel
    2017-10-21
  • Confining Functional Nanoparticles into Colloidal Imine-Based COF Spheres by a Sequential Encapsulation–Crystallization Method 

    Rodríguez-San-Miguel, David; Yazdi, Amirali; Guillerm, Vincent; Pérez-Carvajal, Javier; Puntes, Víctor; Maspoch, Daniel; Zamora, Félix
    2017-06-27
  • Biomimetic Synthesis of Sub-20 nm Covalent Organic Frameworks in Water 

    Franco, Carlos; Rodríguez-San-Miguel, David; Sorrenti, Alessandro; Sevim, Semih; Pons, Ramon; Platero-Prats, Ana; Parlovic, Marko; Szilágyi, Istvan; Ruiz Gonzalez, M. Luisa; González-Calbet, José M.; Bochicchio, Davide; Pesce, Luca; Pavan, Giovanni M.; Imaz, Inhar; Cano-Sarabia, Mary; Maspoch, Daniel; Pané, Salvador; Mello, Andrew J. de; Zamora, Felix; Puigmartí-Luis, Josep
    2020-02-19
All the documents from Biblos-e Archivo are protected by copyrights. Some rights reserved.
Universidad Autónoma de Madrid. Biblioteca
Contact Us | Send Feedback
We are onFacebookCanal BiblosYouTubeTwitterPinterestWhatsappInstagram
 

 

All the documents from Biblos-e Archivo are protected by copyrights. Some rights reserved.
Universidad Autónoma de Madrid. Biblioteca
Contact Us | Send Feedback
We are onFacebookCanal BiblosYouTubeTwitterPinterestWhatsappInstagram