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A MOF@COF Composite with Enhanced Uptake through Interfacial Pore Generation

dc.contributor.authorGarzón-Tovar, Luis
dc.contributor.authorPérez-Carvajal, Javier
dc.contributor.authorYazdi, Amirali
dc.contributor.authorHernández-Muñoz, Jose
dc.contributor.authorTarazona Lafarga, Pedro José 
dc.contributor.authorImaz, Inhar
dc.contributor.authorZamora Abanades, Félix Juan 
dc.contributor.authorMaspoch, Daniel
dc.contributor.otherUAM. Departamento de Física Teórica de la Materia Condensadaes_ES
dc.contributor.otherUAM. Departamento de Química Inorgánicaes_ES
dc.date.accessioned2019-09-30T10:00:14Z
dc.date.available2019-09-30T10:00:14Z
dc.date.issued2019-07-08
dc.identifier.citationAngewandte Chemie - International Edition 58.28 (2019): 9512-9516en_US
dc.identifier.issn1521-3773 (online)en_US
dc.identifier.issn1433-7851 (print)en_US
dc.identifier.urihttp://hdl.handle.net/10486/688694
dc.descriptionThis is the peer reviewed version of the following article: Angewandte Chemie - International Edition 58.28 (2019): 9512-9516, which has been published in final form at https://doi.org/10.1002/ange.201904766. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versionsen_US
dc.descriptionTítulo del postprint: Enhanced Uptake in a MOF@COF Composite by Interfacial Pore Generationes_ES
dc.description.abstractHerein, we describe a new class of porous composites comprising metal–organic framework (MOF) crystals confined in single spherical matrices made of packed covalent-organic framework (COF) nanocrystals. These MOF@COF composites are synthesized through a two-step method of spray-drying and subsequent amorphous (imine-based polymer)-to-crystalline (imine-based COF) transformation. This transformation around the MOF crystals generates micro- and mesopores at the MOF/COF interface that provide far superior porosity compared to that of the constituent MOF and COF components added together. We report that water sorption in these new pores occurs within the same pressure window as in the COF pores. Our new MOF@COF composites, with their additional pores at the MOF/COF interface, should have implications for the development of new compositesen_US
dc.description.sponsorshipThis work was supported by the Spanish MINECO (projects PN MAT2016-77608-C3-1-P, FIS2017-86007-C3 and FPU2015/0248), the Catalan AGAUR (project 2014 SGR 80), the ERC, under EU-FP7 (ERC-Co 615954), and the CERCA Program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV-2017-0706). IFIMAC is supported by the Maria de Maeztu program (Grant No. MDM-2014-0377)en_US
dc.format.extent6 pag.en_US
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherWiley-VCH Verlagen_US
dc.relation.ispartofAngewandte Chemie - International Editionen_US
dc.rights© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.subject.otherMetal-organic frameworksen_US
dc.subject.otherInterfacesen_US
dc.subject.otherHierarchical porosityen_US
dc.subject.otherCovalent-organic frameworksen_US
dc.subject.otherComposite materialsen_US
dc.titleA MOF@COF Composite with Enhanced Uptake through Interfacial Pore Generationen_US
dc.typearticleen
dc.subject.ecienciaQuímicaes_ES
dc.date.embargoend2020-07-08
dc.relation.publisherversionhttps://doi.org/10.1002/ange.201904766es_ES
dc.identifier.doi10.1002/anie.201904766es_ES
dc.identifier.publicationfirstpage9512es_ES
dc.identifier.publicationissue28es_ES
dc.identifier.publicationlastpage9516es_ES
dc.identifier.publicationvolume58es_ES
dc.relation.projectIDGobierno de España. MAT2016-77608-C3-1-Pes_ES
dc.relation.projectIDGobierno de España. FIS2017-86007-C3es_ES
dc.relation.projectIDGobierno de España. FPU2015/0248es_ES
dc.relation.projectIDGobierno de España. SEV-2017-0706es_ES
dc.relation.projectIDGobierno de España. MDM-2014-0377es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/615954en_US
dc.type.versioninfo:eu-repo/semantics/acceptedVersionen
dc.rights.accessRightsopenAccessen
dc.authorUAMZamora Abanades, Félix Juan (258846)
dc.authorUAMHernández Muñoz, José (278888)
dc.authorUAMTarazona Lafarga, Pedro José (259456)
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMCentro de Investigación en Física de la Materia Condensada (IFIMAC)
dc.institutoUAMInstituto de Investigación Avanzada en Ciencias Químicas (IAdChem)


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