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dc.contributor.authorMoreno-Moreno, Miriam
dc.contributor.authorTroyano, Javier
dc.contributor.authorAres, Pablo
dc.contributor.authorCastillo, Oscar
dc.contributor.authorNijhuis, Christian A.
dc.contributor.authorYuan, Li
dc.contributor.authorAmo-Ochoa, Pilar
dc.contributor.authorDelgado, Salomé
dc.contributor.authorGómez-Herrero, Julio
dc.contributor.authorZamora, Félix
dc.contributor.authorGómez-Navarro, Cristina
dc.contributor.otherUAM. Departamento de Física de la Materia Condensadaes_ES
dc.contributor.otherUAM. Departamento de Química Inorgánicaes_ES
dc.date.accessioned2019-10-11T11:25:19Z
dc.date.available2019-10-11T11:25:19Z
dc.date.issued2018-10-23
dc.identifier.citationACS Nano 12.10 (2018): 10171-10177en_US
dc.identifier.issn1936-086X (online)en_US
dc.identifier.issn1936-0851 (print)en_US
dc.identifier.urihttp://hdl.handle.net/10486/688836
dc.descriptionThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Nano, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acsnano.8b05056en_US
dc.description.abstractThe future of 2D flexible electronics relies on the preparation of conducting ultrathin films of materials with mechanical robustness and flexibility in a simple but controlled manner. In this respect, metal-organic compounds present advantages over inorganic laminar crystals owing to their structural, chemical, and functional diversity. While most metal-organic compounds are usually prepared in bulk, recent work has shown that some of them are processable down to low dimensional forms. Here we report the one-pot preparation, carried out at the water-air interface, of ultrathin (down to 4 nm) films of the metal-organic compound [Cu2I2(TAA)]n (TAA= thioacetamide). The films are shown to be homogeneous over mm2 areas, smooth, highly transparent, mechanically robust, and good electrical conductors with memristive behavior at low frequencies. This combination of properties, as well as the industrial availability of the two building blocks required for the preparation, demonstrates their wide range potential in future flexible and transparent electronicsen_US
dc.description.sponsorshipWe acknowledge financial support through the “Marıa de Maeztu” Programme for Units of Excellence in R&D (MDM2014-0377) and from projects MAT2016-77608-C3-1-P and 3-P, MAD2D-CM, MAT2016-75883-C2-1-P and C2-2-P, and MAT2013-46753-C2-2-P, which includes M.M.-M.’s FPI fellowship. Ramon Areces foundation is acknowledged for financial support. We acknowledge the Ministry of Education (MOE) for supporting this research under award no. MOE2015-T2-2-134. Prime Minister’s Office, Singapore under its medium-sized centre program is also acknowledged for supporting this research. The authors would like to acknowledge the Singapore Synchrotron Light Source (SSLS) for providing the facilities at the Surface, Interface, and Nanostructure Science (SINS) beamline under NUS core support C-380-003-003-001. The Laboratory is a National Research Infrastructure under the National Research Foundation Singaporeen_US
dc.format.extent24 pag.en_US
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofACS Nanoen_US
dc.rights© 2018 American Chemical Societyen_US
dc.subject.otherCoordination polymeren_US
dc.subject.otherElectrical conductivityen_US
dc.subject.otherMechanical robustnessen_US
dc.subject.otherMemristive switchingen_US
dc.subject.otherMetal-organic polymeren_US
dc.subject.otherNanofilmsen_US
dc.subject.otherTransparent electrodesen_US
dc.titleOne-Pot Preparation of Mechanically Robust, Transparent, Highly Conductive, and Memristive Metal-Organic Ultrathin Filmen_US
dc.typearticleen
dc.subject.ecienciaFísicaes_ES
dc.subject.ecienciaQuímicaes_ES
dc.date.embargoend2019-10-23
dc.relation.publisherversionhttps://doi.org/10.1021/acsnano.8b05056es_ES
dc.identifier.doi10.1021/acsnano.8b05056es_ES
dc.identifier.publicationfirstpage10171es_ES
dc.identifier.publicationissue10es_ES
dc.identifier.publicationlastpage10177es_ES
dc.identifier.publicationvolume12es_ES
dc.relation.projectIDGobierno de España. MDM2014-0377es_ES
dc.relation.projectIDGobierno de España. MAT2016-77608-C3-1-Pes_ES
dc.relation.projectIDGobierno de España. MAT2016-77608-C3-3-Pes_ES
dc.relation.projectIDGobierno de España. MAT2016-75883-C2-1-Pes_ES
dc.relation.projectIDGobierno de España. MAT2016-75883-C2-2-Pes_ES
dc.relation.projectIDGobierno de España. MAT2013-46753-C2-2-Pes_ES
dc.relation.projectIDComunidad de Madrid. S2013/MIT‐3007/MAD2Des_ES
dc.type.versioninfo:eu-repo/semantics/acceptedVersionen
dc.rights.accessRightsopenAccessen
dc.authorUAMMoreno Moreno, Mirian (263586)
dc.authorUAMAres García, Pablo (260701)
dc.authorUAMAmo Ochoa, María Pilar (261554)
dc.authorUAMDelgado Gil, Salomé (259692)
dc.authorUAMGómez Herrero, Julio (260232)
dc.authorUAMZamora Abanades, Félix Juan (258846)
dc.facultadUAMFacultad de Ciencias
dc.institutoUAMCentro de Investigación en Física de la Materia Condensada (IFIMAC)
dc.institutoUAMInstituto de Investigación Avanzada en Ciencias Químicas (IAdChem)


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