Confining Functional Nanoparticles into Colloidal Imine-Based COF Spheres by a Sequential Encapsulation–Crystallization Method

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dc.contributor.author Rodríguez-San-Miguel, David
dc.contributor.author Yazdi, Amirali
dc.contributor.author Guillerm, Vincent
dc.contributor.author Pérez-Carvajal, Javier
dc.contributor.author Puntes, Víctor
dc.contributor.author Maspoch, Daniel
dc.contributor.author Zamora, Félix
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES
dc.date.accessioned 2019-10-17T08:52:15Z
dc.date.available 2019-10-17T08:52:15Z
dc.date.issued 2017-06-27
dc.identifier.citation Chemistry - A European Journal 23.36 (2017): 8623-8627 en_US
dc.identifier.issn 0947-6539 (print) en_US
dc.identifier.issn 1521-3765 (online) en_US
dc.identifier.uri http://hdl.handle.net/10486/688869
dc.description This is the peer reviewed version of the following article: Rodríguez‐San‐Miguel, D., Yazdi, A., Guillerm, V., Pérez‐Carvajal, J., Puntes, V., Maspoch, D., & Zamora, F. (2017). Confining Functional Nanoparticles into Colloidal Imine‐Based COF Spheres by a Sequential Encapsulation–Crystallization Method. Chemistry–A European Journal, 23(36), 8623-8627, which has been published in final form at https://doi.org/10.1002/chem.201702072. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions en_US
dc.description.abstract Here, a two-step method is reported that enables imparting new functionalities to covalent organic frameworks (COFs) by nanoparticle confinement. The direct reaction between 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-benzenetricarbaldehyde in the presence of a variety of metallic/metal-oxide nanoparticles resulted in embedding of the nanoparticles in amorphous and non-porous imine-linked polymer organic spheres (NP@a-1). Post-treatment reactions of NP@a-1 with acetic acid under reflux led to crystalline and porous imine-based COF-hybrid spheres (NP@c-1). Interestingly, Au@c-1 and Pd@c-1 were found to be catalytically active en_US
dc.description.sponsorship This work was supported by the Spanish MINECO (projects PN MAT2016‐77608‐C3‐1‐P and MAT2015‐65354‐C2‐1‐R), the Catalan AGAUR (project 2014 SGR 80), and the ERC under the EU FP7 (ERC‐Co 615954). V.G. is grateful to the Generalitat de Catalunya for a Beatriu de Pinós fellowship (2014 BP‐B 00155). A.Y. and ICN2 acknowledge the support of the Spanish MINECO through the Severo Ochoa Centers of Excellence Program, under Grant SEV‐2013‐0295 en_US
dc.format.extent 6 pag. en_US
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher Wiley-VCH Verlag en_US
dc.relation.ispartof Chemistry - A European Journal en_US
dc.rights © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim en_US
dc.subject.other Covalent organic frameworks en_US
dc.subject.other Crystallization en_US
dc.subject.other Encapsulation en_US
dc.subject.other Hybrids en_US
dc.subject.other Nanoparticles en_US
dc.title Confining Functional Nanoparticles into Colloidal Imine-Based COF Spheres by a Sequential Encapsulation–Crystallization Method en_US
dc.type article en
dc.subject.eciencia Química es_ES
dc.date.embargoend 2018-06-27
dc.relation.publisherversion https://doi.org/10.1002/chem.201702072 es_ES
dc.identifier.doi 10.1002/chem.201702072 es_ES
dc.identifier.publicationfirstpage 8623 es_ES
dc.identifier.publicationissue 36 es_ES
dc.identifier.publicationlastpage 8627 es_ES
dc.identifier.publicationvolume 23 es_ES
dc.relation.projectID Gobierno de España. MAT2016‐77608‐C3‐1‐P es_ES
dc.relation.projectID Gobierno de España. MAT2015‐65354‐C2‐1‐R es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/615954 en_US
dc.relation.projectID Gobierno de España. SEV‐2013‐0295 es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.accessRights openAccess en
dc.authorUAM Rodríguez San Miguel, David (265015)
dc.authorUAM Zamora Abanades, Félix Juan (258846)


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