Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations

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Show simple item record Castillo, Oscar Delgado, Esther Gómez-García, Carlos J. Hernández, Diego Hernández, Elisa Martín, Avelino Martínez, José I. Zamora, Félix
dc.contributor.other UAM. Departamento de Química Inorgánica es_ES 2019-10-17T10:45:29Z 2019-10-17T10:45:29Z 2017-10-02
dc.identifier.citation Inorganic Chemistry 56.19 (2017): 11810-11818 es_ES
dc.identifier.issn 1520-510X (online) en_US
dc.identifier.issn 0020-1669 (print) en_US
dc.description This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see en_US
dc.description.abstract The use of theoretical calculations has allowed us to predict the coordination behavior of dithiolene [M(SC6H4S)2]2- (M = Ni, Pd, Pt) entities, giving rise to the first organometallic polymers {[K2(μ-H2O)2][Ni(SC6H4S)2]}n and {[K2(μ-H2O)2(thf)]2[K2(μ-H2O)2(thf)2][Pd3(SC6H4S)6]}n by one-pot reactions of the corresponding d10 metal salts, 1,2-benzenedithiolene, and KOH. The polymers are based on σ,π interactions between potassium atoms and [M(SC6H4S)2]2- (M = Ni, Pd) entities. In contrast, only σ interactions are observed when the analogous platinum derivative is used instead, yielding the coordination polymer {[K2(μ-thf)2][Pt(SC6H4S)2]}n en_US
dc.description.sponsorship This work was supported in part by the MICINN (grants MAT2016-77608-C3-1-P and MAT2016-75883-C2-1-P), Generalitat Valenciana (PrometeoII/2014/076), and ISIC. J.I.M. acknowledges financial support by the “Ramon y Cajal ́ ” Program of MINECO (RYC-2015-17730) en_US
dc.format.extent 30 pag. es_ES
dc.format.mimetype application/pdf en
dc.language.iso eng en
dc.publisher American Chemical Society en_US
dc.relation.ispartof Inorganic Chemistry en_US
dc.rights © 2017 American Chemical Society en_US
dc.subject.other Coordination polymers en_US
dc.subject.other Metal-dithiolene polymers en_US
dc.subject.other Coordination compounds en_US
dc.subject.other First-principles calculations en_US
dc.title Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations en_US
dc.type article en
dc.subject.eciencia Química es_ES 2018-10-02
dc.relation.publisherversion es_ES
dc.identifier.doi 10.1021/acs.inorgchem.7b01775 es_ES
dc.identifier.publicationfirstpage 11810 es_ES
dc.identifier.publicationissue 19 es_ES
dc.identifier.publicationlastpage 11818 es_ES
dc.identifier.publicationvolume 56 es_ES
dc.relation.projectID Gobierno de España. MAT2016-77608-C3-1-P es_ES
dc.relation.projectID Gobierno de España. MAT2016-75883-C2-1-P es_ES
dc.relation.projectID Gobierno de España. RYC-2015-17730 es_ES
dc.type.version info:eu-repo/semantics/acceptedVersion en
dc.rights.accessRights openAccess en
dc.authorUAM Delgado Laita, Esther (259693)
dc.authorUAM Zamora Abanades, Félix Juan (258846)

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