Noncovalent Synthesis of Self-Assembled Nanotubes through Decoupled Hierarchical Cooperative Processes
Publisher
American Chemical SocietyDate
2019-10-16Citation
10.1021/jacs.9b07868
Journal of the American Chemical Society 141.41 (2019): 16432-16438
ISSN
1520-5126 (online); 0002-7863 (print)DOI
10.1021/jacs.9b07868Funded by
Funding from the European Research Council (ERC-Starting Grant 279548 PROGRAM-NANO) and MINECO (CTQ2014-57729-P and CTQ2017-84727-P) is gratefully acknowledged. V.V.-G. is grateful to MINECO for a FPI Grant. I.K.V. would like to acknowledge The Netherlands Organization for Scientific Research (NWO VIDI Grant 723.014.006) for financial supportProject
Gobierno de España. CTQ2014-57729-P; Gobierno de España. CTQ2017-84727-P; info:eu-repo/grantAgreement/EC/FP7/279548Editor's Version
https://doi.org/10.1021/jacs.9b07868Subjects
Supramolecular chemistry; Supramolecular polymerization; Self-assembled nanotubes; Cooperativity; QuímicaNote
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.9b07868Rights
© 2019 American Chemical SocietyAbstract
Because of their wide number of biological functions and potential applications, self-assembled nanotubes constitute highly relevant targets in noncovalent synthesis. Herein, we introduce a novel approach to produce supramolecular nanotubes with defined inner and outer diameters from rigid rod-like monomers programmed with complementary nucleobases through two distinct, decoupled cooperative processes of different hierarchy and acting in orthogonal directions: chelate cooperativity, responsible for the formation of robust Watson-Crick H-bonded cyclic tetramers, and nucleation-growth cooperative polymerization
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Google Scholar:Vázquez-González, Violeta
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Mayoral, Maria J.
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Chamorro, Raquel
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Hendrix, Marco M.R.M.
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Voets, Ilja K.
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González Rodríguez, David
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