Perspectives of the smart Cu-Iodine coordination polymers: A portage to the world of new nanomaterials and composites
Entity
UAM. Departamento de Química InorgánicaPublisher
Elsevier B.VDate
2019-02-15Citation
10.1016/j.ccr.2018.11.008
Coordination Chemistry Reviews 381 (2019): 65-78
ISSN
1873-3840 (online); 0010-8545 (print)DOI
10.1016/j.ccr.2018.11.008Funded by
We thank financial support from the Spanish Ministerio de Economía y Competitividad (MINECO), MAT2016-77608-C3-1-P , MAT2016-75883-C2-2-P . JCE acknowledges the financial support by the “FPI-MINECO” Program of MINECO (Grant BES-2015-071534)Project
Gobierno de España. MAT2016-77608-C3-1-P; Gobierno de España. MAT2016-75883-C2-2-PEditor's Version
https://doi.org/10.1016/j.ccr.2018.11.008Subjects
Coordination polymers; Nanomaterials; Smart composites; Smart materials; Stimuli-response materials; QuímicaNote
This Accepted Manuscript will be available for reuse under a CC BY-NC-ND licence after 24 months of embargo periodSupplementary data to this article is available online at: https://doi.org/10.1016/j.ccr.2018.11.008
Rights
© 2018 Elsevier B.V.Esta obra está bajo una licencia de Creative Commons Reconocimiento-NoComercial-SinObraDerivada 4.0 Internacional.
Abstract
This work is focused on the chemistry and physical properties of a particular family of coordination polymers (CPs) based on copper-iodine chains bearing functionalized pyridine, pyrimidine and pyrazine ligands. Although this family of compounds has been well-described, most of the studies have been focused on structural characterization and optical properties in bulk scale while works rationalizing their stimuli-responsive behavior and the role of these materials at the nanoscale are being reported very rencently. This article describes the first works in these fields and the perspectives that nanoscaled CPs based on Cu(I)-halide will have in the near future. Thus, the aim of this review is to present the new perspectives that are opening for these materials by deepening in their behavior, considering theoretical calculations, size-dependent properties or their combination with other components to form new hybrid materials. The combination of all these aspects will allow the discovery of interesting materials useful in sensing, nanochips or packaging, among other uses
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Google Scholar:Conesa-Egea, Javier
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Zamora Abanades, Félix Juan
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Amo Ochoa, María Pilar
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