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Gas–Solid Heterogeneous Postsynthetic Modification of Imine-Based Covalent Organic Frameworks

Author
Martín-Illán, Jesús A.; Royuela, Sergio; Mar Ramos, M.; Segura, José L.; Zamora, Félix
Entity
UAM. Departamento de Química Inorgánica
Date
2020-05-20
Citation
Chemistry – A European Journal 26.29 (2020): 6495-6498
ISSN
1521-3765
DOI
10.1002/chem.202000224
Funded by
This work was financially supported by MINECO (MAT2016‐77608‐C3‐1‐P and 2‐P)
Project
Gobierno de España. MAT2016‐77608‐C3‐1‐P; Gobierno de España. MAT2016‐77608‐C3‐2‐P
Editor's Version
https://doi.org/10.1002/chem.202000224
Subjects
2D materials; Click chemistry; Solvent free reactions; Covalent organic frameworks; Química
URI
http://hdl.handle.net/10486/691093
Note
This is the peer-reviewed version of the following article: Martín-Illian, J. A., Royuela, S., Ramos, M. M., Segura, J. L., & Zamora, F. (2020). Gas‐Solid Heterogeneous Post‐Synthetic Modification of Imine‐based Covalent Organic Frameworks. Chemistry–A European Journal. 26 (29), 6495-6498, which has been published in final form at https://doi.org/10.1002/chem.202000224. This article may be used for non-commercial purposes in accordance with Wiley-VCH Terms and Conditions for Self-Archiving
Rights
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Abstract

The copper-catalyzed azide–alkyne cycloaddition (CuAAC) click reaction is among the most extensively used strategies for the post-polymerization modification of COFs. This work shows a new procedure for the postsynthetic functionalization of imine-based COFs by using a heterogeneous solid–gas reaction between alkyne-functionalized COFs and azides in the absence of a copper catalyst. This new alternative represents a step forward towards a greener postsynthetic modification of COFs opening a high potential for the development of new applications
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Google™ Scholar:Martín-Illán, Jesús A. - Royuela, Sergio - Mar Ramos, M. - Segura, José L. - Zamora, Félix

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